Ferrocenephosphonates: Copper-Promoted Synthesis and Further Functionalization
Résumé
Ferrocenephosphonates make up an important class of organometallic derivatives with a wide range of useful applications in organic synthesis and coordination chemistry. Here, an approach to ferro-cenephosphonates based on a copper-promoted Hirao coupling is reported. Further functionalizations based on regioselective deprotolithiation and both Negishi and Suzuki-Miyaura cross-coupling reactions are also described to reach original derivatives.
Domaines
Chimie de coordination
Fichier principal
Ferrocenephosphonates - Main - HAL.pdf (1.31 Mo)
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Ferrocenephosphonates - ESI - Revised.pdf (7.09 Mo)
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