Colloidal and chemical stabilities of iron oxide nanoparticles in aqueous solutions: the interplay of structural, chemical and environmental drivers - Chimie et Ingénierie des Procédés Accéder directement au contenu
Article Dans Une Revue Environmental science‎.Nano Année : 2018

Colloidal and chemical stabilities of iron oxide nanoparticles in aqueous solutions: the interplay of structural, chemical and environmental drivers

Résumé

Nanoparticle (NP) stability in aqueous environments is dependent upon many parameters including environmental conditions, NP concentrations as well as NP intrinsic characteristics. In this study, the effects of pH and surface modifications on the colloidal and chemical stabilities of nanosized magnetite (Fe3O4), maghemite (γ-Fe2O3) and hematite (α-Fe2O3) are investigated. Because changes in surface charge affect the size distribution of NP, pH plays a key role in driving the colloidal stability. More NP aggregation is observed at pH values close to the pH of zero point of charge (pHzpc). Coating of magnetite with humic acid (HA) and phosphatidylcholine (PC) affects the electrostatic interactions and then the colloidal behavior of NP. The rapid transformation of magnetite into maghemite through air oxidation results in significant modification of both surface charge and specific surface area of NP. Because the maghemite almost exclusively formed µm-scale aggregates, the colloidal stability of magnetite is expected to be hindered in oxic environments. For hematite, the particle size distribution data emphasize the influence of both pH and intrinsic surface properties in the colloidal stability. These findings may have strong implications for an accurate prediction of the transformation and mobility of Fe-nanoparticles under environmentally relevant conditions and thus their fate in nature.

Domaines

Géochimie
Fichier principal
Vignette du fichier
Demangeat2018.pdf (1.18 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

insu-01737100 , version 1 (28-10-2020)

Identifiants

Citer

Edwige Demangeat, Mathieu Pédrot, Aline Dia, Martine Bouhnik-Le Coz, Fabien Grasset, et al.. Colloidal and chemical stabilities of iron oxide nanoparticles in aqueous solutions: the interplay of structural, chemical and environmental drivers. Environmental science‎.Nano, 2018, 5 (4), pp.992-1001. ⟨10.1039/C7EN01159H⟩. ⟨insu-01737100⟩
216 Consultations
361 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More