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Article Dans Une Revue European Journal of Organic Chemistry Année : 2021

Synthesis of 2,2'-Bipyridines through Catalytic C-C Bond Formations from C-H Bonds

Résumé

The present review describes the homogenous catalytic methodologies for the synthesis of 2,2'-bipyridines involving C-C bond formation from C-H bond. There are three main approaches to build well-decorated 2,2'-bipyridines from C-H bond cleavage: i) the formation of C2-C2 ' bond by the dimerization of (activated) pyridines, ii) the C-H bond heteroarylation of activated pyridine, or iii) the late-stage functionalization of (activated) 2,2'-bipyridines including photoredox processes. Besides the scope and limitation of each methodologies, the relevant mechanisms of reaction are also discussed.

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Chimie
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hal-03367745 , version 1 (24-11-2021)

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Wided Hagui, Kiruthika Periasamy, Jean-François Soulé. Synthesis of 2,2'-Bipyridines through Catalytic C-C Bond Formations from C-H Bonds. European Journal of Organic Chemistry, 2021, 2021 (39), pp.5388-5402. ⟨10.1002/ejoc.202100806⟩. ⟨hal-03367745⟩
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