Efficient electron transfer through a triazole link in ruthenium (II) polypyridine type complexes

Aurélie Baron (1) , C. Herrero (2) , A. Quaranta (2) , Charlot M. F. , W. Leibl (2) , B. Vauzeilles , A. Aukauloo

1 ICMMO - Institut de Chimie Moléculaire et des Matériaux d'Orsay
2 SMPSD - Système membranaires, photobiologie, stress et détoxication

Spectroscopic, electrochemical and theoretical characterisations of photoactive systems readily assembled via click-chemistry show an efficient bi-directional charge shift through the triazole link.

Domaines: Catalyse

Aurélie Baron, C. Herrero, A. Quaranta, Charlot M. F., W. Leibl, et al.. Efficient electron transfer through a triazole link in ruthenium (II) polypyridine type complexes. Chemical Communications, 2011, 47, pp.11011-11013. ⟨10.1039/c1cc13683f⟩. ⟨hal-00720029⟩