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The use HPTLC and Direct Analysis in Real Time-Of-Flight Mass Spectrometry DART-TOF-MS for rapid analysis of degradation by oxidation and sonication of an azo dye

Abstract : Advanced oxidation processes are efficient for the removal of recalcitrant compounds, like azo-dyes. However, the intermediates produced during their degradation can be more toxic than the parent compounds. Improving the knowledge concerning the degradation pathways may be therefore helpful to optimize the process. In this aim, HPTLC and Direct Analysis in Real Time-Of-Flight Mass Spectrometry DART-TOF-MS were considered and applied to analyze the sono-oxidation of an azo dye, methyl red sodium salt (MRSS) as a model compound. Initial and final UV-Vis spectra showed a clear disappearance of the maximum absorption peak, but shows limit since it cannot allow by-products identification. MRSS degradation was confirmed by HPTLC, which also confirmed that MRSS degradation was mainly due to oxidation, while in the considered experimental conditions the sonication effect appeared negligible. Three major peaks were observed by DART-TOF-MS after MRSS oxidation, m/z=139.002, m/z=223.073 and m/z=279.137, Relative abundance of m/z=139.002, which was much higher after oxidation, tends to prove that a large proportion of initial oxydized MRSS was fragmented. The MRSS m/z = 270.078. The coupling of HPTLC and DART-TOF-MS may be subsequently considered to identify the oxidation reaction products.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-00840315
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Submitted on : Friday, July 5, 2013 - 2:18:23 PM
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Hayet Djelal, Carole Cornée, Ronan Tardivel, Olivier Lavastre, Abdelatif Amrane. The use HPTLC and Direct Analysis in Real Time-Of-Flight Mass Spectrometry DART-TOF-MS for rapid analysis of degradation by oxidation and sonication of an azo dye. Arabian Journal of Chemistry, Elsevier, 2017, 10 (Supplement 2), pp.S1619-S1628. ⟨10.1016/j.arabjc.2013.06.003⟩. ⟨hal-00840315⟩

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