1. Hz, 30 (s, 3H) 13 C NMR (100 MHz, CDCl 3 ): ? 140, Hz, 1H), 7.31 (t, J = 7.3 Hz, 1H)

. Mhz, 39 (s, 3H) 13 C NMR (100 MHz, CDCl 3 ): ? 150(3-Methylbenzo[b]thiophen-2-yl)-isoquinoline (29) From 4-bromoisoquinoline (0.208 g, 1 mmol) and 3-methyl- g) yield as a yellow oil, pp.8-5380

J. =d and J. =. , 274 g, 1.5 mmol), 32 was obtained in 85% (0.249 g) yield as a white solid (mp 137-138 °C) 1 H NMR (400 MHz CDCl 3 ): ? 730 (s, 3H) 13 C NMR (100 MHz, CDCl 3 ): ? 142(4-tert-Butylphenyl)-3-methyl-benzo[b]thiophene (33) From 1-tert-butylbromobenzene (0.213 g, 1 mmol) and 5-chloro- 3-methylbenzothiophene (0.274 g, 1.5 mmol), 33 was obtained in 58% (0.182 g) yield as a white solid (mp 134-136 °C). 1 H NMR (400 MHz, CDCl 3 ): ? 7, (d, J = 8.3 Hz, 1H) 4H), 7.22 (d, J = 8.3 Hz, 1H), 2.36 (s, 3H), 1.30 (s, 9H). 13 C NMR (100 MHz

1. Hz, 13 C NMR (100 MHz CDCl 3 ): ? 141, p.25

1. Hz, J. =dd, and J. =. , (dd, J = 8.5, 1.8 Hz, 1H), 2.30 (s, 3H) 13 C NMR (100 MHz, CDCl 3 ): ? 150, 1920.

1. Hz, 13 C NMR (100 MHz CDCl 3 ): ? 138

M. Akita, Y. Ohkuwa, T. Chiba, M. Fukunaga, R. Miyafuji et al., CDCl 3 ): ? 140 Supporting information Copies of 1 H and 13 C NMR spectra of new compounds. References 1, (d, J = 8.5 Hz, 2H), 7.12 (d, J = 8.5 Hz, 2H). 13 C NMR (100 MHz, pp.1951-1958, 1990.

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