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A facile route to steady redox-modulated nitroxide spin-labeled surfaces based on diazonium chemistry.

Abstract : A TEMPO derivative was covalently grafted onto carbon and gold surfaces via the diazonium chemistry. The acid-dependent redox properties of the nitroxyl group were exploited to elaborate electro-switchable magnetic surfaces. ESR characterization demonstrated the reversible and permanent magnetic character of the material.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-00855600
Contributor : Béatrice Mahi <>
Submitted on : Thursday, August 29, 2013 - 4:23:58 PM
Last modification on : Wednesday, September 16, 2020 - 11:16:02 AM

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Charles Cougnon, Séverine Boisard, Olivier Cador, Marylène Dias, Eric Levillain, et al.. A facile route to steady redox-modulated nitroxide spin-labeled surfaces based on diazonium chemistry.. Chemical Communications, Royal Society of Chemistry, 2013, 49 (40), pp.4555-7. ⟨10.1039/c3cc40768c⟩. ⟨hal-00855600⟩

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