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Journal articles

A facile route to steady redox-modulated nitroxide spin-labeled surfaces based on diazonium chemistry.

Charles Cougnon 1 Séverine Boisard 1 Olivier Cador 2 Marylène Dias 3 Eric Levillain 3 Tony Breton 4 
1 MOLTECH-Anjou
2 ISCR - Institut des Sciences Chimiques de Rennes
3 CIMMA - Chimie, Ingénierie Moléculaire et Matériaux d'Angers
4 LACCO - Laboratoire de catalyse en chimie organique
Abstract : A TEMPO derivative was covalently grafted onto carbon and gold surfaces via the diazonium chemistry. The acid-dependent redox properties of the nitroxyl group were exploited to elaborate electro-switchable magnetic surfaces. ESR characterization demonstrated the reversible and permanent magnetic character of the material.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-00855600
Contributor : Béatrice Mahi Connect in order to contact the contributor
Submitted on : Thursday, August 29, 2013 - 4:23:58 PM
Last modification on : Friday, June 24, 2022 - 3:48:39 AM

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UNIV-RENNES1 | CNRS | UNIV-ANGERS | UNIV-POITIERS | INSA-RENNES | ISCR | ISCR-OMC | INC-CNRS | UR1-UFR-SPM | UNIV-RENNES | INSA-GROUPE | MOLTECH-ANJOU | UR1-MMS

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Charles Cougnon, Séverine Boisard, Olivier Cador, Marylène Dias, Eric Levillain, et al.. A facile route to steady redox-modulated nitroxide spin-labeled surfaces based on diazonium chemistry.. Chemical Communications, Royal Society of Chemistry, 2013, 49 (40), pp.4555-7. ⟨10.1039/c3cc40768c⟩. ⟨hal-00855600⟩

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