Skip to Main content Skip to Navigation
Journal articles

Perfluorocyclohexene bridges in inverse DiArylEthenes: synthesis through Pd-catalysed C-H bond activation, experimental and theoretical studies on their photoreactivity.

Abstract : The palladium-catalysed direct di-heteroarylation of 1,2-dichloroperfluorocyclohexene with a variety of heteroarenes gives rise in to a new family of 1,2-di(heteroaryl)perfluorocyclohexenes. These derivatives do not exhibit photoreactivity and this unexpected outcome is explained by calculations demonstrating the lack of reactive isomers.
Document type :
Journal articles
Complete list of metadatas

Cited literature [14 references]  Display  Hide  Download

https://hal-univ-rennes1.archives-ouvertes.fr/hal-00860214
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, September 10, 2014 - 7:00:04 AM
Last modification on : Thursday, March 5, 2020 - 2:06:49 PM
Long-term archiving on: : Thursday, December 11, 2014 - 11:35:38 AM

Files

DA-Cycle6-rev-accepted.pdf
Files produced by the author(s)

Identifiers

Citation

Kedong Yuan, Julien Boixel, Hubert Le Bozec, Abdou Boucekkine, Henri Doucet, et al.. Perfluorocyclohexene bridges in inverse DiArylEthenes: synthesis through Pd-catalysed C-H bond activation, experimental and theoretical studies on their photoreactivity.. Chemical Communications, Royal Society of Chemistry, 2013, 49 (72), pp.7896-8. ⟨10.1039/c3cc43754j⟩. ⟨hal-00860214⟩

Share

Metrics

Record views

745

Files downloads

487