Redox-induced reversible P-P bond formation to generate an organometallic σ4λ4-1,2-biphosphane dication.

Ayham Tohmé (1) , Guillaume Grelaud (1) , Gilles Argouarch (1) , Thierry Roisnel (1) , Stéphanie Labouille (2) , Duncan Carmichael (2) , Frédéric Paul (1)

1 ISCR - Institut des Sciences Chimiques de Rennes
2 DCPH - Laboratoire Hétéroéléments et Coordination

Mots clés: iron; dimerization; molecular electronics; phosphorus; radical reactions

Domaines: Catalyse

Ayham Tohmé, Guillaume Grelaud, Gilles Argouarch, Thierry Roisnel, Stéphanie Labouille, et al.. Redox-induced reversible P-P bond formation to generate an organometallic σ4λ4-1,2-biphosphane dication.. Angewandte Chemie International Edition, 2013, 52 (16), pp.4445-8. ⟨10.1002/anie.201208682⟩. ⟨hal-00878561⟩