Syntheses of Cu(I) polymetallic assemblies from reaction of ligands bearing the 2,5-bis(2-pyridyl)phosphole fragment with Cu(II) precursors.

Mehdi El Sayed Moussa; Fabian Friess; Wenting Shen; Muriel Hissler; Régis Réau; Christophe Lescop

doi:10.1039/c3cc42955e

Journal articles

Syntheses of Cu(I) polymetallic assemblies from reaction of ligands bearing the 2,5-bis(2-pyridyl)phosphole fragment with Cu(II) precursors.

Mehdi El Sayed Moussa ¹ Fabian Friess ¹ Wenting Shen ¹ Muriel Hissler ¹ Régis Réau ¹ Christophe Lescop ^{1, *}

* Corresponding author

1 ISCR - Institut des Sciences Chimiques de Rennes

Abstract : Upon reaction with ligands A, 1 and 3 bearing the 2,5-bis(2-pyridyl)phosphole fragment, an unexpected conversion of Cu(II) metal centers to Cu(I) centers is observed affording either bimetallic complexes bearing a bridging phosphane coordination mode or hexametallic metallacycles.

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Journal articles

Domain :

Chemical Sciences / Catalysis

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https://hal-univ-rennes1.archives-ouvertes.fr/hal-00878617
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Submitted on : Wednesday, October 30, 2013 - 1:23:56 PM
Last modification on : Thursday, March 5, 2020 - 2:05:44 PM

Syntheses of Cu(I) polymetallic assemblies from reaction of ligands bearing the 2,5-bis(2-pyridyl)phosphole fragment with Cu(II) precursors.

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Syntheses of Cu(I) polymetallic assemblies from reaction of ligands bearing the 2,5-bis(2-pyridyl)phosphole fragment with Cu(II) precursors.

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