T. Kurita, Y. Nishimori, F. Toshimitsu, S. Muratsugu, S. Kume et al., Surface Junction Effects on the Electron Conduction of Molecular Wires, Journal of the American Chemical Society, vol.132, issue.13, pp.4524-4525, 2010.
DOI : 10.1021/ja910462x

K. Seo, A. V. Konchenko, J. Lee, G. S. Bang, and H. Lee, Molecular Conductance Switch-On of Single Ruthenium Complex Molecules, Journal of the American Chemical Society, vol.130, issue.8, pp.2553-2559, 2008.
DOI : 10.1021/ja077089u

K. Terada, H. Nakamura, K. Kanaizuka, M. Haga, Y. Asai et al., a Stepping-Stone Mechanism, ACS Nano, vol.6, issue.3, pp.1988-1999, 2012.
DOI : 10.1021/nn300126m

J. Madoz, B. A. Kuznetzov, F. J. Medrano, J. L. Garcia, and V. M. Fernandez, Functionalization of Gold Surfaces for Specific and Reversible Attachment of a Fused ??-Galactosidase and Choline-Receptor Protein, Journal of the American Chemical Society, vol.119, issue.5, pp.1043-1051, 1997.
DOI : 10.1021/ja963465r

J. P. Collman, N. K. Devaraj, R. A. Decreau, Y. Yang, Y. L. Yan et al., A Cytochrome c Oxidase Model Catalyzes Oxygen to Water Reduction Under Rate-Limiting Electron Flux, Science, vol.315, issue.5818, pp.1565-1568, 2007.
DOI : 10.1126/science.1135844

A. L. Eckermann, D. J. Feld, J. A. Shaw, and T. J. Meade, Electrochemistry of redox-active self-assembled monolayers, Coordination Chemistry Reviews, vol.254, issue.15-16, pp.1769-1802, 2010.
DOI : 10.1016/j.ccr.2009.12.023

C. Vericat, M. E. Vela, G. Benitez, P. Carro, and R. C. Salvarezza, Self-assembled monolayers of thiols and dithiols on gold: new challenges for a well-known system, Chemical Society Reviews, vol.25, issue.part 2, pp.1805-1834, 2010.
DOI : 10.1039/b907301a

J. C. Love, L. A. Estroff, J. K. Kriebel, R. G. Nuzzo, and G. M. Whitesides, Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology, Chemical Reviews, vol.105, issue.4, pp.1103-1169, 2005.
DOI : 10.1021/cr0300789

N. K. Devaraj, R. A. Decreau, W. Ebina, J. P. Collman, and C. E. Chidsey, Rate of Interfacial Electron Transfer through the 1,2,3-Triazole Linkage, The Journal of Physical Chemistry B, vol.110, issue.32, pp.15955-15962, 2006.
DOI : 10.1021/jp057416p

D. J. Feld, H. T. Hsu, A. L. Eckermann, and T. J. Meade, Trinuclear Ruthenium Clusters as Bivalent Electrochemical Probes for Ligand???Receptor Binding Interactions, Langmuir, vol.28, issue.1, pp.939-949, 2012.
DOI : 10.1021/la202882k

B. Kim, J. M. Beebe, C. Olivier, S. Rigaut, D. Touchard et al., Temperature and Length Dependence of Charge Transport in Redox-Active Molecular Wires Incorporating Ruthenium(II) Bis(??-arylacetylide) Complexes, The Journal of Physical Chemistry C, vol.111, issue.20, pp.7521-7526, 2007.
DOI : 10.1021/jp068824b

URL : https://hal.archives-ouvertes.fr/hal-01475544

N. Tuccitto, V. Ferri, M. Cavazzini, S. Quici, G. Zhavnerko et al., Highly conductive ???40-nm-long molecular wires??assembled by stepwise incorporation of??metal??centres, Nature Materials, vol.1, issue.1, pp.41-46, 2009.
DOI : 10.1039/b613347a

V. Arima, M. Iurlo, L. Zoli, S. Kumar, M. Piacenza et al., Toward quantum-dot cellular automata units: thiolated-carbazole linked bisferrocenes, Nanoscale, vol.98, issue.3, pp.813-823, 2012.
DOI : 10.1039/C1NR10988J

C. S. Lent, B. Isaksen, and M. Lieberman, Molecular Quantum-Dot Cellular Automata, Journal of the American Chemical Society, vol.125, issue.4, pp.1056-1063, 2003.
DOI : 10.1021/ja026856g

J. Y. Jiao, G. J. Long, F. Grandjean, A. M. Beatty, and T. P. Fehlner, Building Blocks for the Molecular Expression of Quantum Cellular Automata. Isolation and Characterization of a Covalently Bonded Square Array of Two Ferrocenium and Two Ferrocene Complexes, Journal of the American Chemical Society, vol.125, issue.25, pp.7522-7523, 2003.
DOI : 10.1021/ja035077c

S. B. Braun-sand and O. Wiest, Biasing Mixed-Valence Transition Metal Complexes in Search of Bistable Complexes for Molecular Computing, The Journal of Physical Chemistry B, vol.107, issue.36, pp.9624-9628, 2003.
DOI : 10.1021/jp034208t

S. B. Braun-sand and O. Wiest, Theoretical Studies of Mixed-Valence Transition Metal Complexes for Molecular Computing, The Journal of Physical Chemistry A, vol.107, issue.2, pp.285-291, 2003.
DOI : 10.1021/jp0265945

Z. H. Li, A. M. Beatty, and T. P. Fehlner, Molecular QCA Cells. 1. Structure and Functionalization of an Unsymmetrical Dinuclear Mixed-Valence Complex for Surface Binding, Inorganic Chemistry, vol.42, issue.18, pp.5707-5714, 2003.
DOI : 10.1021/ic026254y

Z. H. Li and T. P. Fehlner, Molecular QCA Cells. 2. Characterization of an Unsymmetrical Dinuclear Mixed-Valence Complex Bound to a Au Surface by an Organic Linker, Inorganic Chemistry, vol.42, issue.18, pp.5715-5721, 2003.
DOI : 10.1021/ic026255q

J. Y. Jiao, G. J. Long, L. Rebbouh, F. Grandjean, A. M. Beatty et al., Square Cell for Utilization in the Quantum Cellular Automata Paradigm for Molecular Electronics, Journal of the American Chemical Society, vol.127, issue.50, pp.17819-17831, 2005.
DOI : 10.1021/ja0550935

B. Schneider, S. Demeshko, S. Dechert, and F. Meyer, A Double-Switching Multistable Fe4 Grid Complex with Stepwise Spin-Crossover and Redox Transitions, Angewandte Chemie International Edition, vol.49, issue.48, pp.9274-9277, 2010.
DOI : 10.1002/anie.201001536

C. Orain, N. L. Poul, A. Gomila, J. M. Kerbaol, N. Cosquer et al., A Generic Platform for the Addressable Functionalisation of Electrode Surfaces through Self-Induced ???Electroclick???, Chemistry - A European Journal, vol.53, issue.2, pp.594-602, 2012.
DOI : 10.1002/chem.201102620

URL : https://hal.archives-ouvertes.fr/hal-01175769

J. M. Casas-solvas, A. Vargas-berenguel, L. F. Capitan-vallvey, and F. Santoyo-gonzalez, Convenient Methods for the Synthesis of Ferrocene???Carbohydrate Conjugates, Organic Letters, vol.6, issue.21, pp.3687-3690, 2004.
DOI : 10.1021/ol048665j

J. P. Collman, N. K. Devaraj, and C. E. Chidsey, ???Clicking??? Functionality onto Electrode Surfaces, Langmuir, vol.20, issue.4, pp.1051-1053, 2004.
DOI : 10.1021/la0362977

Y. G. Lee, G. M. Morales, and L. P. Yu, Self-Assembled Monolayers of Isocyanides on Nickel Electrodes, Angewandte Chemie International Edition, vol.14, issue.27, pp.4228-4231, 2005.
DOI : 10.1002/anie.200500942

U. T. Muellerwesterhoff, Z. Yang, and G. Ingram, A simple synthesis of metallocene aldehydes from lithiometallocenes and N,N-dimethylformamide: Ferrocene and ruthenocene aldehydes and 1,1???-dialdehydes, Journal of Organometallic Chemistry, vol.463, issue.1-2, pp.163-167, 1993.
DOI : 10.1016/0022-328X(93)83414-Q

M. F. Abasiyanik and M. Senel, Immobilization of glucose oxidase on reagentless ferrocene-containing polythiophene derivative and its glucose sensing application, Journal of Electroanalytical Chemistry, vol.639, issue.1-2, pp.21-26, 2010.
DOI : 10.1016/j.jelechem.2009.11.001

E. Lieber, C. N. Rao, T. S. Chao, and C. W. Hoffman, Infrared Spectra of Organic Azides, Analytical Chemistry, vol.29, issue.6, pp.916-918, 1957.
DOI : 10.1021/ac60126a016

D. W. Hall and C. D. Russell, Substituent effects in the chronopotentiometric oxidation of ferrocene derivatives. Internal solvation of certain substituted ferricenium ions, Journal of the American Chemical Society, vol.89, issue.10, pp.2316-2322, 1967.
DOI : 10.1021/ja00986a012

A. C. Ribou, J. P. Launay, M. L. Sachtleben, H. Li, and C. W. Spangler, Intervalence Electron Transfer in Mixed Valence Diferrocenylpolyenes. Decay Law of the Metal???Metal Coupling with Distance, Inorganic Chemistry, vol.35, issue.13, pp.3735-3740, 1996.
DOI : 10.1021/ic951376u

G. Ferguson, C. Glidewell, G. Opromolla, C. M. Zakaria, and P. Zanello, The redox behaviour of some bis-ferrocenyl compounds: crystal and molecular structures of diferrocenylmethane and diferrocenylmethanol, Journal of Organometallic Chemistry, vol.517, issue.1-2, pp.183-190, 1996.
DOI : 10.1016/0022-328X(96)06199-2

B. J. Hathaway and D. E. Billing, The electronic properties and stereochemistry of mono-nuclear complexes of the copper(II) ion, Coordination Chemistry Reviews, vol.5, issue.2, pp.143-207, 1970.
DOI : 10.1016/S0010-8545(00)80135-6

A. A. Gewirth, S. L. Cohen, H. J. Schugar, and E. I. Solomon, Spectroscopic and theoretical studies of the unusual EPR parameters of distorted tetrahedral cupric sites: correlations to x-ray spectral features of core levels, Inorganic Chemistry, vol.26, issue.7, pp.1133-1146, 1987.
DOI : 10.1021/ic00254a032

P. F. Schwab and J. R. Smith, Synthesis and Properties of Molecular Rods. 2. Zig-Zag Rods, Chemical Reviews, vol.105, issue.4, pp.1197-1279, 2005.
DOI : 10.1021/cr040707u

P. Aguirre-etcheverry and D. O-'hare, Electronic Communication through Unsaturated Hydrocarbon Bridges in Homobimetallic Organometallic Complexes, Chemical Reviews, vol.110, issue.8, pp.4839-4864, 2010.
DOI : 10.1021/cr9003852

S. Barlow and D. Ohare, Metal???Metal Interactions in Linked Metallocenes, Chemical Reviews, vol.97, issue.3, pp.637-669, 1997.
DOI : 10.1021/cr960083v

M. J. Powers and T. J. Meyer, Intervalence transfer in mixed-valence biferrocene ions, Journal of the American Chemical Society, vol.100, issue.14, pp.4393-4398, 1978.
DOI : 10.1021/ja00482a013

W. Kaim, A. Klein, and M. Glockle, Exploration of Mixed-Valence Chemistry:?? Inventing New Analogues of the Creutz-Taube Ion, Accounts of Chemical Research, vol.33, issue.11, pp.755-763, 2000.
DOI : 10.1021/ar960067k

P. F. Hapiot, L. D. Kispert, V. V. Konovalov, and J. M. Saveant, Single Two-Electron Transfers vs Successive One-Electron Transfers in Polyconjugated Systems Illustrated by the Electrochemical Oxidation and Reduction of Carotenoids, Journal of the American Chemical Society, vol.123, issue.27, pp.6669-6677, 2001.
DOI : 10.1021/ja0106063

N. S. Hush, Homogeneous and heterogeneous optical and thermal electron transfer, Electrochimica Acta, vol.13, issue.5, pp.1005-1023, 1968.
DOI : 10.1016/0013-4686(68)80032-5

N. S. Hush, Distance Dependence of Electron Transfer Rates, Coordination Chemistry Reviews, vol.64, pp.135-157, 1985.
DOI : 10.1016/0010-8545(85)80047-3

J. P. Collman, N. K. Devaraj, T. P. Eberspacher, and C. E. Chidsey, Mixed Azide-Terminated Monolayers:?? A Platform for Modifying Electrode Surfaces, Langmuir, vol.22, issue.6, pp.2457-2464, 2006.
DOI : 10.1021/la052947q

E. Laviron, General expression of the linear potential sweep voltammogram in the case of diffusionless electrochemical systems, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol.101, issue.1, pp.19-28, 1979.
DOI : 10.1016/S0022-0728(79)80075-3

E. Laviron and L. Roullier, General expression of the linear potential sweep voltammogram for a surface redox reaction with interactions between the adsorbed molecules, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol.115, issue.1, pp.65-74, 1980.
DOI : 10.1016/S0022-0728(80)80496-7

C. E. Chidsey, Free Energy and Temperature Dependence of Electron Transfer at the Metal-Electrolyte Interface, Science, vol.251, issue.4996, pp.919-922, 1991.
DOI : 10.1126/science.251.4996.919

K. Weber, L. Hockett, and S. Creager, Long-Range Electronic Coupling between Ferrocene and Gold in Alkanethiolate-based Monolayers on Electrodes, The Journal of Physical Chemistry B, vol.101, issue.41, pp.8286-8291, 1997.
DOI : 10.1021/jp9717103

C. P. Hsu and R. A. Marcus, A sequential formula for electronic coupling in long range bridge-assisted electron transfer: Formulation of theory and application to alkanethiol monolayers, The Journal of Chemical Physics, vol.106, issue.2, pp.584-598, 1997.
DOI : 10.1063/1.473398