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Helicene-grafted vinyl- and carbene-osmium complexes: an example of acid-base chiroptical switching

Abstract : The first helicene-based carbene-osmium complex has been prepared from a vinyl-osmium derivative and this system has been shown to behave as a potential acid-base triggered chiroptical switch.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01058225
Contributor : Muriel Cadieu <>
Submitted on : Tuesday, August 26, 2014 - 12:20:23 PM
Last modification on : Thursday, March 5, 2020 - 2:07:20 PM
Long-term archiving on: : Tuesday, April 11, 2017 - 8:26:50 PM

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Emmanuel Anger, Monika Srebro, Nicolas Vanthuyne, Christian Roussel, Loïc Toupet, et al.. Helicene-grafted vinyl- and carbene-osmium complexes: an example of acid-base chiroptical switching. Chemical Communications, Royal Society of Chemistry, 2014, 50 (22), pp.2854-2856. ⟨10.1039/C3CC47825D⟩. ⟨hal-01058225⟩

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