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Journal articles
Synthesis, photovoltaic performances and TD-DFT modeling of push-pull diacetylide platinum complexes in TiO2 based dye-sensitized solar cells.
Sébastien Gauthier
1
Bertrand Caro
1
Françoise Robin-Le Guen
1
Nattamai Bhuvanesh
2
John A Gladysz
2
Laurianne Wojcik
3
Nicolas Le Poul
3
Aurélien Planchat
4
Yann Pellegrin
4
Errol Blart
4
Denis Jacquemin
4
Fabrice Odobel
4
Sébastien Gauthier 1
Author
Bertrand Caro 1
Author
Françoise Robin-Le Guen 1
Author
Nattamai Bhuvanesh 2
Author
John A Gladysz 2
Author
Laurianne Wojcik 3
Author IdHAL : laurianne-wojcik ORCID : https://orcid.org/0000-0002-7897-4142
Nicolas Le Poul 3
Author IdHAL : nicolas-le-poul ORCID : https://orcid.org/0000-0002-5915-3760
Aurélien Planchat 4
Author
1
ISCR - Institut des Sciences Chimiques de Rennes (Campus de Beaulieu - Bât. 10 Avenue du Général Leclerc 35042 Rennes Cedex - France)
- UR1 - Université de Rennes 1 (2 rue du Thabor - CS 46510 - 35065 Rennes cedex - France)
- UNIV-RENNES - Université de Rennes (France)
- INSA Rennes - Institut National des Sciences Appliquées - Rennes (20, avenue des Buttes de Coësmes - CS 70839 - 35708 Rennes cedex 7 - France)
- Ecole Nationale Supérieure de Chimie de Rennes (France)
- CNRS - Centre National de la Recherche Scientifique : UMR6226 (France)
2
Department of Chemistry, Texas University (P.O. Box 30012, College Station, TX 77842-3012 - United States)
- Texas University (France)
3
CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique (6 Av Victor Le Gorgeu - BP 809 29285 BREST CEDEX - France)
- UBO - Université de Brest (Université de Bretagne Occidentale - 3 Rue des Archives 29238, Brest - France)
- INC - Institut de Chimie du CNRS (3 Rue Michel-Ange 75 016 Paris - France)
- CNRS - Centre National de la Recherche Scientifique : UMR6521 (France)
- IBSAM - Institut Brestois Santé Agro Matière (Université de Brest- UBO
29238 Brest - France)
- UBO - Université de Brest (Université de Bretagne Occidentale - 3 Rue des Archives 29238, Brest - France)
4
CEISAM - Chimie Et Interdisciplinarité : Synthèse, Analyse, Modélisation (UFR des Sciences et des Techniques - 2 rue de la Houssiniere BP 92208 - 44322 NANTES Cedex 3 - France)
- Université de Nantes - Faculté des Sciences et des Techniques (2, rue de la Houssinière - BP 92208 - 44322 Nantes cedex 3 - France)
- UN - Université de Nantes (1, quai de Tourville - BP 13522 - 44035 Nantes cedex 1 - France)
- CNRS - Centre National de la Recherche Scientifique : UMR6230 (France)
Abstract : In this joint experimental-theoretical work, we present the synthesis and optical and electrochemical characterization of five new bis-acetylide platinum complex dyes end capped with diphenylpyranylidene moieties, as well as their performances in dye-sensitized solar cells (DSCs). Theoretical calculations relying on Time-Dependent Density Functional Theory (TD-DFT) and a range-separated hybrid show a very good match with experimental data and allow us to quantify the charge-transfer character of each compound. The photoconversion efficiency obtained reaches 4.7% for 8e (see TOC Graphic) with the tri-thiophene segment, which is among the highest efficiencies reported for platinum complexes in DSCs.
Document type :
Journal articles
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Complete list of metadatas
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01114401
Contributor : Laurent Jonchère <>
Submitted on : Monday, February 9, 2015 - 1:38:57 PM
Last modification on : Wednesday, January 13, 2021 - 3:07:43 AM
Contributor : Laurent Jonchère <>
Submitted on : Monday, February 9, 2015 - 1:38:57 PM
Last modification on : Wednesday, January 13, 2021 - 3:07:43 AM
Identifiers
- HAL Id : hal-01114401, version 1
- DOI : 10.1039/c4dt00301b
- PUBMED : 24837848
Collections
UNIV-RENNES1 | UNIV-BREST | UNIV-NANTES | CNRS | ISCR | ISCR-OMC | INC-CNRS | UR1-UFR-SPM | CEMCA-BREST | UNIV-RENNES | INSA-GROUPE | IBSAM | INSA-RENNES
Citation
Sébastien Gauthier, Bertrand Caro, Françoise Robin-Le Guen, Nattamai Bhuvanesh, John A Gladysz, et al.. Synthesis, photovoltaic performances and TD-DFT modeling of push-pull diacetylide platinum complexes in TiO2 based dye-sensitized solar cells.. Dalton Transactions, Royal Society of Chemistry, 2014, 43 (29), pp.11233-42. ⟨10.1039/c4dt00301b⟩. ⟨hal-01114401⟩
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