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[(NHC)Fe(CO)4] Efficient Pre-catalyst for Selective Hydroboration of Alkenes

Abstract : [(IMes)Fe(CO)4] [IMes=1,3-bis(2,4,6-trimethylphenyl) imidazol-2-ylidene] complex was found to be an efficient pre-catalyst for the hydroboration of functional alkenes in the presence of pinacolborane at room temperature. Notably, UV irradiation (350 nm) is important to promote this catalytic transformation. Interestingly, high chemo- and regioselectivities were observed as only anti-Markovnikov boronate derivatives were obtained and various functional groups can be tolerated.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01114927
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Submitted on : Tuesday, February 10, 2015 - 11:35:00 AM
Last modification on : Friday, July 10, 2020 - 4:21:47 PM

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Jianxia Zheng, Jean-Baptiste Sortais, Christophe Darcel. [(NHC)Fe(CO)4] Efficient Pre-catalyst for Selective Hydroboration of Alkenes. ChemCatChem, Wiley, 2014, 6 (3), pp.763-766. ⟨10.1002/cctc.201301062⟩. ⟨hal-01114927⟩

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