A self-assembled bis(pyrrolo)tetrathiafulvalene-based redox active squarew

Jean-Yves Balandier (1) , Marcos Chas , Sebastien Goeb , Paul I. Dron , David Rondeau (2) , Ahmed Belyasmine (3) , Nuria Gallego , Marc Salle (3)

1 Laboratoire de Chimie des Polymères (ULB)
2 IETR - Institut d'Électronique et des Technologies du numéRique
3 CIMMA - Chimie, Ingénierie Moléculaire et Matériaux d'Angers

The synthesis and full characterization of a redox-active p-donating molecular square is described, through coordination-driven self-assembly of a new key bis(pyrrolo)TTF building block with Pt(II) salts; the electrochemical behaviour of the square is consistent with noninteracting bis(pyrrolo)TTF units.

Domaines: Chimie; Matériaux

Jean-Yves Balandier, Marcos Chas, Sebastien Goeb, Paul I. Dron, David Rondeau, et al.. A self-assembled bis(pyrrolo)tetrathiafulvalene-based redox active squarew. New Journal of Chemistry, 2010, 35, pp.165-168. ⟨10.1039/c0nj00545b⟩. ⟨hal-01122049⟩