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High temperature sublimation of α-amino acids: a realistic prebiotic process leading to large enantiomeric excess.

Abstract : The reiterative high temperature co-sublimation of an enantiopure or an enantioenriched α-amino acid mixed with racemic α-amino acids leads to deracemization of the latter. A synergistic effect is observed for complex mixtures, and the sense of the handedness is, for all compounds, identical to that of the enantioenriched starting material.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01137939
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, March 31, 2015 - 5:17:01 PM
Last modification on : Thursday, March 5, 2020 - 2:06:46 PM

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Arkadii V Tarasevych, Alexander E Sorochinsky, Valery P Kukhar, Jean-Claude Guillemin. High temperature sublimation of α-amino acids: a realistic prebiotic process leading to large enantiomeric excess.. Chemical Communications, Royal Society of Chemistry, 2015, 51 (32), pp.7054-7057. ⟨10.1039/C5CC00254K⟩. ⟨hal-01137939⟩

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