Sequential double second-order nonlinear optical switch by an acido-triggered photochromic cyclometallated platinum(ii) complex.

Julien Boixel (1) , Véronique Guerchais (1) , Hubert Le Bozec (1) , Agisilaos Chantzis (2) , Denis Jacquemin (3, 2) , Alessia Colombo (4) , Claudia Dragonetti (5, 4) , Daniele Marinotto (5) , Dominique Roberto (4, 5)

1 ISCR - Institut des Sciences Chimiques de Rennes
2 CEISAM - Chimie Et Interdisciplinarité : Synthèse, Analyse, Modélisation
3 IUF - Institut Universitaire de France
4 Dipartimento di Chimica
5 CNR ISTM

An unprecedented DTE-based Pt(II) complex, 2(o), which stands as the first example of a sequential double nonlinear optical switch, induced first by protonation and next upon irradiation with UV light is presented.

Domains: Chemical Sciences

Julien Boixel, Véronique Guerchais, Hubert Le Bozec, Agisilaos Chantzis, Denis Jacquemin, et al.. Sequential double second-order nonlinear optical switch by an acido-triggered photochromic cyclometallated platinum(ii) complex.. Chemical Communications, 2015, 51 (37), pp.7805-7808. ⟨10.1039/C5CC01893E⟩. ⟨hal-01141732⟩