A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic nonlinear optical properties.
Abstract
A new Zn(ii) porphyrin-cored ruthenium alkynyl dendrimer (2) containing twelve Ru(κ2-dppe)2 bis-alkynyl fragments has been prepared in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(ii) and shown to be highly active for third-harmonic generation (THG) at 1907 nm
Domains
Chemical Sciences
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Hybrid Ruthenium Alkynyl Zinc Porphyrin_accepted.pdf (344.74 Ko)
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Hybrid Ruthenium Alkynyl Zinc Porphyrin_supplementary material.pdf (511.37 Ko)
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Origin : Files produced by the author(s)
Origin : Files produced by the author(s)