A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic nonlinear optical properties.

Areej Merhi; Guillaume Grelaud; Katy A Green; Ngo Hoang Minh; Michael Reynolds; Isabelle Ledoux; Adam Barlow; Genmiao Wang; Marie P Cifuentes; Mark G Humphrey; Frédéric Paul; Christine O Paul-Roth

doi:10.1039/C5DT00768B

Journal articles

A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic nonlinear optical properties.

Areej Merhi ¹ Guillaume Grelaud ^{2, 1} Katy A Green ² Ngo Hoang Minh ³ Michael Reynolds ³ Isabelle Ledoux ^{3, *} Adam Barlow ² Genmiao Wang ² Marie P Cifuentes ² Mark G Humphrey ^{2, *} Frédéric Paul ^{1, *} Christine O Paul-Roth ^{1, *}

* Corresponding author

1 ISCR - Institut des Sciences Chimiques de Rennes

2 Research School of Chemistry

3 LPQM - Laboratoire de Photonique Quantique et Moléculaire

Abstract : A new Zn(ii) porphyrin-cored ruthenium alkynyl dendrimer (2) containing twelve Ru(κ2-dppe)2 bis-alkynyl fragments has been prepared in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(ii) and shown to be highly active for third-harmonic generation (THG) at 1907 nm

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Journal articles

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Chemical Sciences

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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01142055
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Submitted on : Thursday, September 10, 2015 - 10:27:52 AM
Last modification on : Wednesday, September 16, 2020 - 5:00:00 PM
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A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic nonlinear optical properties.

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A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic nonlinear optical properties.

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