Crystal Structure of the Radical-Cation Salt (o-Me2TTF)I3 with Close Intermolecular Sulfur Contacts. - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Journal of Chemical Crystallography Année : 2009

Crystal Structure of the Radical-Cation Salt (o-Me2TTF)I3 with Close Intermolecular Sulfur Contacts.

Eric W. Reinheimer
  • Fonction : Auteur
Marc Fourmigué
Kim R. Dunbar
  • Fonction : Auteur

Résumé

The synthesis and crystal structure of the org. radical-cation salt (o-Me2TTF)I3 is described. The salt crystallizes in the monoclinic space group P2 1 /n with a = 10.927(2) Å, b = 11.904(2) Å, c = 12.660(2) Å, β = 115.174(5)°. The bond length of the central C=C bond in o-Me2TTF is 1.401(1) Å, indicating an approx. oxidn. state of +1 for the o-Me2TTF radical cation. Graphical Abstr. The X-ray crystallog. structure of the radical cation salt (o-Me2TTF)I3 has been detd. and its structural properties and synthetic prepn. are discussed.

Dates et versions

hal-01151565 , version 1 (13-05-2015)

Identifiants

Citer

Eric W. Reinheimer, Marc Fourmigué, Kim R. Dunbar. Crystal Structure of the Radical-Cation Salt (o-Me2TTF)I3 with Close Intermolecular Sulfur Contacts.. Journal of Chemical Crystallography, 2009, 39, pp.735--739. ⟨10.1007/s10870-009-9520-5⟩. ⟨hal-01151565⟩
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