Skip to Main content Skip to Navigation
Journal articles

First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH:CH-py)2·2CH3CN, M = CoII, MnII.

Abstract : The first paramagnetic homo- and hetero-metallic trinuclear complexes, [Co2M(PhCOO)6(L)2]·2MeCN \M = Co, Mn; L = 4-[2-(tetrathiafulvalenyl)ethenyl]pyridine\ with redox active ligands derived from TTF were synthesized and structurally characterized. The central metal ion has an octahedral coordination sphere while the outer CoII ions are in a distorted bipyramidal surrounding, bearing TTF-ligands. The magnetic properties show antiferromagnetic coupling leading to a magnetic ground state.
Document type :
Journal articles
Complete list of metadatas

https://hal-univ-rennes1.archives-ouvertes.fr/hal-01151569
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, May 13, 2015 - 10:22:04 AM
Last modification on : Thursday, March 5, 2020 - 2:05:48 PM

Links full text

Identifiers

Citation

Konstantin S. Gavrilenko, Yann Le Gal, Olivier Cador, Stéphane Golhen, Lahcene Ouahab. First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH:CH-py)2·2CH3CN, M = CoII, MnII.. Chemical Communications, Royal Society of Chemistry, 2007, pp.280--282. ⟨10.1039/B613191C⟩. ⟨hal-01151569⟩

Share

Metrics

Record views

224