First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH:CH-py)2·2CH3CN, M = CoII, MnII. - Archive ouverte HAL Access content directly
Journal Articles Chemical Communications Year : 2007

First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH:CH-py)2·2CH3CN, M = CoII, MnII.

Abstract

The first paramagnetic homo- and hetero-metallic trinuclear complexes, [Co2M(PhCOO)6(L)2]·2MeCN \M = Co, Mn; L = 4-[2-(tetrathiafulvalenyl)ethenyl]pyridine\ with redox active ligands derived from TTF were synthesized and structurally characterized. The central metal ion has an octahedral coordination sphere while the outer CoII ions are in a distorted bipyramidal surrounding, bearing TTF-ligands. The magnetic properties show antiferromagnetic coupling leading to a magnetic ground state.

Dates and versions

hal-01151569 , version 1 (13-05-2015)

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Konstantin S. Gavrilenko, Yann Le Gal, Olivier Cador, Stéphane Golhen, Lahcene Ouahab. First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH:CH-py)2·2CH3CN, M = CoII, MnII.. Chemical Communications, 2007, pp.280--282. ⟨10.1039/B613191C⟩. ⟨hal-01151569⟩
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