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Journal Articles Journal of the American Chemical Society Year : 2015

Iron-Catalyzed C-H Borylation of Arenes.


Well-defined iron bis(diphosphine) complexes are active catalysts for the dehydrogenative C-H borylation of aromatic and heteroaromatic derivatives with pinacolborane. The corresponding borylated compounds were isolated in moderate to good yields (25-73%) with a 5 mol% catalyst loading under UV irradiation (350 nm) at room temperature. Stoichiometric reactivity studies and isolation of an original trans-hydrido(boryl)iron complex, Fe(H)(Bpin)(dmpe)2, allowed us to propose a mechanism showing the role of some key catalytic species.
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hal-01153417 , version 1 (19-05-2015)



Thomas Dombray, C. Gunnar Werncke, Shi Jiang, Mary Grellier, Laure Vendier, et al.. Iron-Catalyzed C-H Borylation of Arenes.. Journal of the American Chemical Society, 2015, 137 (12), pp.4062-4065. ⟨10.1021/jacs.5b00895⟩. ⟨hal-01153417⟩
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