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Crystal structure of 2-(1H-imidazol-4-yl)ethanaminium chloride

Abstract : The title mol-ecular salt, C5H10N3 (+)·Cl(-), was obtained as by-product in the attempted synthesis of a histamine derivative. The terminal amino group of the starting material is protonated. The Cimidazole-C-C-N(H3)(+) group in the cation is in an anti conformation with a torsion angle of 176.22 (10)°. In the crystal, cations and anions are linked via N-H(midline ellipsis)N and N-H-Cl hydrogen bonds, forming a two-dimensional network parallel to (10-1). A single weak C-H(midline ellipsis)Cl hydrogen bond completes a three-dimensional network
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Contributor : Laurent Jonchère Connect in order to contact the contributor
Submitted on : Wednesday, May 27, 2015 - 1:25:06 PM
Last modification on : Monday, January 31, 2022 - 5:22:04 PM

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Imene Belfilali, Siham Yebdri, Samira Louhibi, Leila Boukli-Hacene, Thierry Roisnel. Crystal structure of 2-(1H-imidazol-4-yl)ethanaminium chloride. Acta crystallographica Section E : Crystallographic communications [2015-..], 2015, 71 (5), pp.o301--2. ⟨10.1107/S2056989015006866⟩. ⟨hal-01156435⟩



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