Barium-Mediated Cross-Dehydrocoupling of Hydrosilanes with Amines
Abstract
Alkaline-earth (most prominently barium) complexes of the type [Ae{N(SiMe3 )2 }2 ⋅(THF)x ] and [{N^N}Ae{N(SiMe3 )2 }⋅(THF)x ] are very active and productive precatalysts (TON=396, TOF up to 3600 h(-1) ; Ca
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Submitted on : Wednesday, December 15, 2021-12:25:19 PM
Last modification on : Friday, March 10, 2023-4:18:27 PM
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Identifiers
- HAL Id : hal-01158456 , version 1
- DOI : 10.1002/anie.201502956
- PUBMED : 26013402
Cite
Clément Bellini, Jean-François Carpentier, Sven Tobisch, Yann Sarazin. Barium-Mediated Cross-Dehydrocoupling of Hydrosilanes with Amines. Angewandte Chemie International Edition, 2015, 54 (26), pp.7679 - 7683. ⟨10.1002/anie.201502956⟩. ⟨hal-01158456⟩
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