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First Copper(II) Phase M´0.2Mn0.8PS3• 0.25H2O and Analogous M´= CoII, NiII and ZnII Materials Obtained by Microwave Assisted Synthesis

Abstract : M'0.2Mn0.8PS3·0.25H2O materials are obtained by a mild microwave assisted reaction (M' = Co(II), Ni(II), Cu(II), Zn(II)), which permitted us to obtain the first copper(ii) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS3.
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Submitted on : Thursday, December 17, 2015 - 10:10:06 AM
Last modification on : Friday, July 10, 2020 - 4:03:17 PM
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Pablo Fuentealba, Catalina Cortes, Nathalie Audebrand, Eric Le Fur, Verónica Paredes-García, et al.. First Copper(II) Phase M´0.2Mn0.8PS3• 0.25H2O and Analogous M´= CoII, NiII and ZnII Materials Obtained by Microwave Assisted Synthesis. Dalton Transactions, Royal Society of Chemistry, 2015, 44 (28), pp.12493-12496. ⟨10.1039/C5DT01540E⟩. ⟨hal-01162343⟩

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