. Ed, S. L. Suib, L. Liu, R. Wu, M. Jackstell et al., (b) Activation of carbon dioxide, in New and Future Developments in Catalysis, Nat. Commun, vol.1, issue.2 6, p.414, 2010.

C. Huang, Z. Sun, and . Shi, Transition-metal-catalyzed C???C bond formation through the fixation of carbon dioxide, Chemical Society Reviews, vol.49, issue.5, pp.2435-2452, 2011.
DOI : 10.1039/c0cs00129e

B. Yu, Z. Diao, C. Guo, L. He, S. Paul et al., Journal of CO 2 Utilization, Chem. Commun. Chem. Rev. Dalton Trans. Chem. Commun. Chem. Rev, vol.1, issue.107, pp.60-68, 2007.

A. D. Darensbourg and . Yeung, A concise review of computational studies of the carbon dioxide???epoxide copolymerization reactions, Polymer Chemistry, vol.31, issue.13, pp.3949-3962, 2014.
DOI : 10.1039/c3cy00955f

). E. Kawatrad, J. E. Stechel, and . Miller, Journal of CO 2 Utilization (e) Special Issue: Metal Mediated Transformation of CO 2 , Polyhedron, 2012, 32. (f) Special Issue, Journal of CO 2 Utilization Fifth International Conference on Carbon Dioxide Utilization (ICCDU V), pp.69-87, 2001.

A. L. Lapidus, S. D. Pirojkov, and A. A. Koryakin, and references cited therein, Bull. Acad. Sci. USSR, Div. Chem. Sci. Angew. Chem. Int, vol.19, pp.2514-2516, 1978.

Q. Liu, L. Wu, I. Fleisher, D. Selent, R. Franke et al., Development of a Ruthenium/Phosphite Catalyst System for Domino Hydroformylation-Reduction of Olefins with Carbon Dioxide, Chemistry - A European Journal, vol.212, issue.23, pp.6888-6894, 2014.
DOI : 10.1002/chem.201400358

J. Bringmann, E. Dinjus, S. Derien, E. Dunach, and J. Perichon, Electrochemical synthesis of carboxylic acids from alkenes using various nickel-organic mediators: CO2 as C1-synthon, Applied Organometallic Chemistry, vol.47, issue.2, pp.135-140, 1988.
DOI : 10.1002/1099-0739(200102)15:2<135::AID-AOC108>3.0.CO;2-L

G. Filardo, S. Gambino, G. Silvestri, A. Gennaro, and E. Vianello, Electrocarboxylation of styrene through homogeneous redox catalysis, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol.177, issue.1-2, pp.303-309, 1984.
DOI : 10.1016/0022-0728(84)80232-6

H. Hoberg, K. Jenni, K. K. Angermund, and C. Kruger, CC-Linkages of Ethene with CO2 on an Iron(0) Complex???Synthesis and Crystal Structure Analysis of[(PEt3)2Fe(C2H4)2], Angewandte Chemie International Edition in English, vol.26, issue.2, pp.153-155, 1978.
DOI : 10.1002/anie.198701531

Z. R. Greenburg, D. Jin, P. G. Williard, W. H. Bernskoetter, and D. Trans, 32 A thermally stable metallalactone complex of Ti(IV) has been reported to be the product of the reaction of the parent Ti, II) precursor Cp * 2 Ti(? 2 ?C 2 H 4 ) and CO 2, pp.15990-15996, 1985.

H. G. Alt and C. E. Denner, Zr(II)-metallocenes have been used for the synthesis of the corresponding Zr(IV) zirconalactone complexes: (a), J. Organomet. Chem, vol.390, pp.53-60, 1990.

H. Hoberg and A. Ballesteros, Ni0-induzierte Herstellung cyclischer C8-Carbons??uren aus Cyclooctenen und Kohlendioxid, Journal of Organometallic Chemistry, vol.411, issue.1-2, pp.11-18, 1991.
DOI : 10.1016/0022-328X(91)86033-M

H. Hoberg, Y. Peres, C. Kruger, and Y. Tsay, A 1-Oxa-2-nickela-5-cyclopentanone from Ethene and Carbon Dioxide: Preparation, Structure, and Reactivity, Angewandte Chemie International Edition in English, vol.26, issue.8, pp.771-773, 1987.
DOI : 10.1002/anie.198707711

J. E. Louie, M. V. Gibby, T. N. Farnworth, and . Tekavec, and Diynes, Journal of the American Chemical Society, vol.124, issue.51, pp.15188-15189, 2002.
DOI : 10.1021/ja027438e

D. C. Graham, C. Mitchell, M. I. Bruce, G. F. Metha, J. H. Bowie et al., Production of Acrylic Acid through Nickel-Mediated Coupling of Ethylene and Carbon Dioxide???A DFT Study, Organometallics, vol.26, issue.27, pp.6784-6792, 2007.
DOI : 10.1021/om700592w

C. Bruckmeier, M. W. Lehenmeier, R. Reichardt, S. Vagin, and B. Rieger, and Ethylene via Methylation of Nickelalactones, Organometallics, vol.29, issue.10, pp.2199-2202, 2010.
DOI : 10.1021/om100060y

S. Y. Lee, M. Cokoja, M. Drees, Y. Li, J. Mink et al., Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide, ChemSusChem, vol.14, issue.186, pp.1275-1279, 2011.
DOI : 10.1002/cssc.201000445

W. Guo, C. Michel, R. Schiedernoch, R. Wischert, X. Xu et al., on Ni Complexes: A Mechanistic Viewpoint from a Hybrid DFT Approach, Organometallics, vol.33, issue.22, pp.6369-6380, 2014.
DOI : 10.1021/om5006808
URL : https://hal.archives-ouvertes.fr/hal-01230737

P. N. Plessow, L. Weigel, R. Linder, A. Schafer, F. Rominger et al., , Ethylene and Methyl Iodide, Organometallics, vol.32, issue.11, pp.3327-3338, 2013.
DOI : 10.1021/om400262b

D. Jin, T. J. Schmeier, P. G. Williard, N. Hazari, and W. H. Bernskoetter, and Ethylene, Organometallics, vol.32, issue.7, pp.2152-2159, 2013.
DOI : 10.1021/om400025h

D. Jin, P. G. Williard, N. Hazari, and W. H. Bernskoetter, -Ethylene Coupling to Acrylates, Chemistry - A European Journal, vol.15, issue.11, pp.3205-3211, 2014.
DOI : 10.1002/chem.201304196
URL : https://hal.archives-ouvertes.fr/hal-01058920

E. M. O-'brien, E. A. Bercot, and T. Rovis, Carbon in the Cross-Coupling Event, Journal of the American Chemical Society, vol.125, issue.35, pp.10498-10499, 2003.
DOI : 10.1021/ja036290b

G. Schubert and I. Papai, :?? Reaction Mechanism as Revealed from Density Functional Calculations, Journal of the American Chemical Society, vol.125, issue.48, pp.14847-14858, 2003.
DOI : 10.1021/ja035791u

Y. Zhang, B. S. Hanna, A. Dineen, P. G. Williard, and W. H. Bersnkoetter, Functionalization of Carbon Dioxide with Ethylene at Molybdenum Hydride Complexes, Organometallics, vol.32, issue.14, pp.3969-3979, 2013.
DOI : 10.1021/om400448m

J. M. Wolfe and W. H. Bernskoetter, Reductive functionalization of carbon dioxide to methyl acrylate at zerovalent tungsten, Dalton Transactions, vol.11, issue.35, pp.10763-10768, 2012.
DOI : 10.1039/c2dt31032e

M. Aresta, C. Pastore, P. Giannoccaro, G. Kovacs, A. Dibenedetto et al., Evidence for Spontaneous Release of Acrylates from a Transition-Metal Complex Upon Coupling Ethene or Propene with a Carboxylic Moiety or CO2, Chemistry - A European Journal, vol.107, issue.32, pp.9028-9034, 2007.
DOI : 10.1002/chem.200700532

G. Yang, B. Schaffner, M. Blug, E. J. Hensen, and E. A. Pidko, A Mechanistic Study of Ni-catalyzed Carbon Dioxide Coupling with Ethylene towards the Manufacture of Acrylic Acid, ChemCatChem, vol.105, issue.3, pp.800-807, 2014.
DOI : 10.1002/cctc.201301051

J. B. Johnson and T. Rovis, Enantioselective Cross-Coupling of Anhydrides with Organozinc Reagents: The Controlled Formation of Carbon???Carbon Bonds through the Nucleophilic Interception of Metalacycles, Accounts of Chemical Research, vol.41, issue.2, pp.327-338, 2008.
DOI : 10.1021/ar700176t

L. J. Goossen, N. Rodriguez, F. Manjolinho, and P. P. Lange, Synthesis of Propiolic Acids via Copper-Catalyzed Insertion of Carbon Dioxide into the C???H Bond of Terminal Alkynes, Advanced Synthesis & Catalysis, vol.12, issue.17, pp.2913-2917, 2010.
DOI : 10.1002/adsc.201000564

L. Zhang, J. Cheng, B. Carry, and Z. Hou, Catalytic Boracarboxylation of Alkynes with Diborane and Carbon Dioxide by an N-Heterocyclic Carbene Copper Catalyst, Journal of the American Chemical Society, vol.134, issue.35, pp.14314-14317, 2012.
DOI : 10.1021/ja3063474

T. Fujihara, Y. Tani, K. Semba, J. Terao, and Y. Tsuji, Copper-Catalyzed Silacarboxylation of Internal Alkynes by Employing Carbon Dioxide and Silylboranes, Angewandte Chemie International Edition, vol.131, issue.46, pp.11487-11490, 2012.
DOI : 10.1002/anie.201207148

F. Manjolinho, M. Arndt, K. Gossen, and L. J. Goossen, Catalytic C???H Carboxylation of Terminal Alkynes with Carbon Dioxide, ACS Catalysis, vol.2, issue.9, pp.2014-2021, 2012.
DOI : 10.1021/cs300448v

A. Behr, U. Kanne, and W. Keim, Alcohols as CO/H2 sources in ruthenium-catalyzed hydroesterification, Journal of Molecular Catalysis, vol.35, issue.1, pp.19-28, 1986.
DOI : 10.1016/0304-5102(86)85053-2

Y. Zhang and S. N. Riduan, Catalytic Hydrocarboxylation of Alkenes and Alkynes with CO2, Angewandte Chemie International Edition, vol.48, issue.28, pp.6210-6212, 2011.
DOI : 10.1002/anie.201101341

T. Fujihara, T. Xu, K. Semba, J. Terano, Y. J. Tsuji-)-r et al., Copper-Catalyzed Hydrocarboxylation of Alkynes Using Carbon Dioxide and Hydrosilanes, Angewandte Chemie International Edition, vol.29, issue.2, pp.523-527, 2011.
DOI : 10.1002/anie.201006292

. Org, . Lettc-)-t, S. Mizuta, Y. Sakaguchi, Y. P. Ishii et al., 77 (a) I. Dincer, C. AcarHydrogen, 1. Properties and Occurrence". Ullmann's Encyclopedia of Industrial Chemistry, J. Org. Chem. International journal of Hydrogen Energy Chem. Soc. Rev, vol.13, issue.40, pp.584-587, 2005.

B. D. Darvent, N. S. Werkmeister, K. Junge, M. Beller, and M. , 80 Organic Chemistry Portal, Stand. Ref. Data Ser., Nat. Bur. Stand. (U.S.) Org. Process Res. Dev, vol.18, pp.52-289, 1970.

. Mimoun, Selective Reduction of Carbonyl Compounds by Polymethylhydrosiloxane in the Presence of Metal Hydride Catalysts, The Journal of Organic Chemistry, vol.64, issue.7, pp.2582-2589, 1999.
DOI : 10.1021/jo982314z

M. A. Esteruelas, O. Nurnberg, M. Olivan, L. A. Oro, and H. Werner, Synthesis and reactions of new hydridosilyliridium(III) complexes containing the diolefin tetrafluorobenzobarrelene, Organometallics, vol.12, issue.8, pp.3264-3272, 1993.
DOI : 10.1021/om00032a056

G. Sattler and G. Parkin, -Promoted Displacement of Siloxide Ligands, Journal of the American Chemical Society, vol.133, issue.25, pp.9708-9711, 2011.
DOI : 10.1021/ja2035706
URL : https://hal.archives-ouvertes.fr/hal-01383352

A. Thompson, A. D. Ellern, . Sadow, D. Acs-catal, A. Mukherjee et al., -6 and references therein cited, and references therein cited, pp.698-702, 1998.
URL : https://hal.archives-ouvertes.fr/in2p3-00025581