Palladium-Catalysed Direct Arylation using Free-Amine-Substituted Polyfluoroanilines with Inhibition of Amination-Type Reaction

Abdelilah Takfaoui; Rachid Touzani; Jean-François Soulé; Pierre H. Dixneuf; Henri Doucet

doi:10.1002/ajoc.201500268

Journal articles

Palladium-Catalysed Direct Arylation using Free-Amine-Substituted Polyfluoroanilines with Inhibition of Amination-Type Reaction

Abdelilah Takfaoui ^{1, 2} Rachid Touzani ^{3, 1} Jean-François Soulé ² Pierre H. Dixneuf ² Henri Doucet ²

1 LCAE-URAC18 - Laboratoire de Chimie Appliquée et Environnement

2 ISCR - Institut des Sciences Chimiques de Rennes

3 Faculté Pluridisciplinaire de Nador

Abstract : The palladium-catalyzed C-C bond formation via direct arylation of free-amine-substituted polyfluoroaniline derivs. proceeds in moderate to high yields with a variety of aryl bromides. The nature of the base was found to be crucial to promote the direct arylation with inhibition of the amination reaction.

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Journal articles

Domain :

Chemical Sciences

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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01188225
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Submitted on : Friday, August 28, 2015 - 4:25:34 PM
Last modification on : Wednesday, January 13, 2021 - 3:13:53 AM

Palladium-Catalysed Direct Arylation using Free-Amine-Substituted Polyfluoroanilines with Inhibition of Amination-Type Reaction

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Palladium-Catalysed Direct Arylation using Free-Amine-Substituted Polyfluoroanilines with Inhibition of Amination-Type Reaction

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