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Palladium-Catalysed Direct Arylation using Free-Amine-Substituted Polyfluoroanilines with Inhibition of Amination-Type Reaction

Abdelilah Takfaoui 1, 2 Rachid Touzani 3, 1 Jean-François Soulé 2 Pierre H. Dixneuf 2 Henri Doucet 2
1 LCAE-URAC18 - Laboratoire de Chimie Appliquée et Environnement
2 ISCR - Institut des Sciences Chimiques de Rennes
3 Faculté Pluridisciplinaire de Nador
Abstract : The palladium-catalyzed C-C bond formation via direct arylation of free-amine-substituted polyfluoroaniline derivs. proceeds in moderate to high yields with a variety of aryl bromides. The nature of the base was found to be crucial to promote the direct arylation with inhibition of the amination reaction.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01188225
Contributor : Laurent Jonchère <>
Submitted on : Friday, August 28, 2015 - 4:25:34 PM
Last modification on : Thursday, March 5, 2020 - 2:02:30 PM

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Abdelilah Takfaoui, Rachid Touzani, Jean-François Soulé, Pierre H. Dixneuf, Henri Doucet. Palladium-Catalysed Direct Arylation using Free-Amine-Substituted Polyfluoroanilines with Inhibition of Amination-Type Reaction. Asian Journal of Organic Chemistry, Wiley, 2015, 4 (10), pp.1085-1095. ⟨10.1002/ajoc.201500268⟩. ⟨hal-01188225⟩

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