C. C. Tanner, J. P. Sukias, T. R. Headley, C. R. Yates, and R. Stott, Constructed wetlands and denitrifying bioreactors for on-site and decentralised wastewater treatment: Comparison of five alternative configurations, Ecological Engineering, vol.42, pp.42-112, 2012.
DOI : 10.1016/j.ecoleng.2012.01.022

W. H. Strosnider, B. K. Winfrey, and R. W. Nairn, Biochemical oxygen demand and nutrient processing in a novel multi-stage raw municipal wastewater and acid mine drainage passive co-treatment system, Water Research, vol.45, issue.3, pp.45-1079, 2011.
DOI : 10.1016/j.watres.2010.10.026

P. Molle, A. Lienard, A. Grasmick, A. Iwema, and A. Kabbabi, Apatite as an interesting seed to remove phosphorus from wastewater in constructed wetlands, Water Sci. Technol, pp.51-193, 2005.

G. Lyngsie, O. K. Borggaard, and H. C. Hansen, A three-step test of phosphate sorption efficiency of potential agricultural drainage filter materials, Water Research, vol.51, pp.256-265, 2014.
DOI : 10.1016/j.watres.2013.10.061

Y. Kuwahara, S. Tamagawa, T. Fujitani, and H. Yamashita, A novel conversion process for waste slag: synthesis of calcium silicate hydrate from blast furnace slag and its application as a versatile adsorbent for water purification, Journal of Materials Chemistry A, vol.272, issue.210, pp.7199-7210, 2013.
DOI : 10.1039/c3ta11064h

K. Barthélémy, S. Naille, C. Despas, C. Ruby, and M. Mallet, Carbonated ferric green rust as a new material for efficient phosphate removal, Journal of Colloid and Interface Science, vol.384, issue.1, pp.121-127, 2012.
DOI : 10.1016/j.jcis.2012.06.038

A. F. De-sousa, T. P. Braga, E. C. Gomes, A. Valentini, and E. Longhinotti, Adsorption of phosphate using mesoporous spheres containing iron and aluminum oxide, Chemical Engineering Journal, vol.210, pp.210-143, 2012.
DOI : 10.1016/j.cej.2012.08.080

W. Driehaus, Method for producing a sorption material that contains iron, 2002.

I. N. Savina, C. J. English, R. L. Whitby, Y. Zheng, A. Leistner et al., High efficiency removal of dissolved As(III) using iron nanoparticle-embedded macroporous polymer composites, Journal of Hazardous Materials, vol.192, issue.3, pp.192-1002, 2011.
DOI : 10.1016/j.jhazmat.2011.06.003

K. Mandel, A. Drenkova-tuhtan, F. Hutter, C. Gellermann, H. Steinmetz et al., Layered double hydroxide ion exchangers on superparamagnetic microparticles for recovery of phosphate from waste water, J. Mater. Chem. A, vol.128, issue.5, pp.1840-1848, 2013.
DOI : 10.1039/C2TA00571A

J. Xie, Z. Wang, D. Wu, and H. Kong, Synthesis and properties of zeolite/hydrated iron oxide composite from coal fly ash as efficient adsorbent to simultaneously retain cationic and anionic pollutants from water, Fuel, vol.116, pp.71-76, 2014.
DOI : 10.1016/j.fuel.2013.07.126

M. Arias, J. Da-silva-carballal, L. García-río, J. Mejuto, and A. Núñez, Retention of phosphorus by iron and aluminum-oxides-coated quartz particles, Journal of Colloid and Interface Science, vol.295, issue.1, pp.65-70, 2006.
DOI : 10.1016/j.jcis.2005.08.001

Z. Shi, F. Liu, and S. Yao, Adsorptive removal of phosphate from aqueous solutions using activated carbon loaded with Fe(III) oxide, pp.26-299, 2011.

S. Naille, K. Barthélémy, M. Mallet, and C. Ruby, Method for producing a filtration material, 2014.

M. Mallet, K. Barthélémy, C. Ruby, A. Renard, and S. Naille, Investigation of phosphate adsorption onto ferrihydrite by X-ray Photoelectron Spectroscopy, Journal of Colloid and Interface Science, vol.407, pp.95-101, 2013.
DOI : 10.1016/j.jcis.2013.06.049

URL : https://hal.archives-ouvertes.fr/hal-01503750

R. M. Cornell and U. Schwertmann, The iron oxides: Structure, properties, reactions, occurrences and uses, 2003.
DOI : 10.1002/3527602097

. Parise, Similarities in 2-and 6-line ferrihydrite based on pair distribution function analysis of X-ray total scattering, Chem. Mat, vol.19, pp.1489-1496, 2007.

H. Guo and A. S. Barnard, Naturally occurring iron oxide nanoparticles: morphology, surface chemistry and environmental stability, J. Mater. Chem. A, vol.93, issue.67, pp.27-42, 2013.
DOI : 10.1039/C2TA00523A

S. Das, M. J. Hendry, and J. , Essilfie-Dughan, Transformation of two-line ferrihydrite to goethite and hematite as a function of pH and temperature, Environ. Sci. Technol, pp.45-268, 2010.

E. M. Moon and C. L. Peacock, Adsorption of Cu(II) to ferrihydrite and ferrihydrite???bacteria composites: Importance of the carboxyl group for Cu mobility in natural environments, Geochimica et Cosmochimica Acta, vol.92, pp.203-219, 2012.
DOI : 10.1016/j.gca.2012.06.012

V. Khare, M. Mullet, K. Hanna, M. Blumers, M. Abdelmoula et al., Comparative studies of ferric green rust and ferrihydrite coated sand: Role of synthesis routes, Solid State Sciences, vol.10, issue.10, pp.1342-1351, 2008.
DOI : 10.1016/j.solidstatesciences.2008.01.033

M. Wencka, A. Jelen, M. Jagodi?, V. Khare, C. Ruby et al., Magnetic and EPR study of ferric green rust- and ferrihydrite-coated sand prepared by different synthesis routes, Journal of Physics D: Applied Physics, vol.42, issue.24, p.42, 2009.
DOI : 10.1088/0022-3727/42/24/245301

M. Sardin, D. Schweich, F. J. Leij, and M. T. Van-genuchten, Modeling the Nonequilibrium Transport of Linearly Interacting Solutes in Porous Media: A Review, Water Resources Research, vol.22, issue.5, pp.27-2287, 1991.
DOI : 10.1029/91WR01034

A. C. Ambrosini, G. E. Cismasu, and . Brown, Ordered ferrimagnetic form of ferrihydrite reveals links among structure, composition, and magnetism, Proc. Natl. Acad. Sci. U. S. A, vol.107, pp.2787-2792, 2010.

N. Pinney, J. D. Kubicki, D. S. Middlemiss, C. P. Grey, and D. Morgan, Density Functional Theory Study of Ferrihydrite and Related Fe-Oxyhydroxides, Chemistry of Materials, vol.21, issue.24, pp.5727-5742, 2009.
DOI : 10.1021/cm9023875

K. M. Towe and W. F. Bradley, Mineralogical constitution of colloidal ???hydrous ferric oxides???, Journal of Colloid and Interface Science, vol.24, issue.3, pp.384-392, 1967.
DOI : 10.1016/0021-9797(67)90266-4

B. L. Schoonen, J. B. Phillips, and . Parise, The structure of ferrihydrite, a nanocrystalline material, Science, vol.316, pp.1726-1729, 2007.

S. J. Smith, H. Page, B. J. Kim, J. Campbell, B. F. Boerio-goates et al., Novel Synthesis and Structural Analysis of Ferrihydrite, Inorganic Chemistry, vol.51, issue.11, pp.51-6421, 2012.
DOI : 10.1021/ic300937f

M. Edwards and M. M. Benjamin, Adsorptive filtration using coated sand: A new approach for treatment of metal-bearing wastes, J. Water Pollut. Control Fed, pp.61-1523, 1989.

J. Brillet, M. Gratzel, and K. Sivula, Decoupling Feature Size and Functionality in Solution-Processed, Porous Hematite Electrodes for Solar Water Splitting, Nano Letters, vol.10, issue.10, pp.4155-4160, 2010.
DOI : 10.1021/nl102708c

B. Plante, M. Benzaazoua, B. Bussière, M. C. Biesinger, and A. R. Pratt, Study of Ni sorption onto Tio mine waste rock surfaces, Applied Geochemistry, vol.25, issue.12, pp.25-1830, 2010.
DOI : 10.1016/j.apgeochem.2010.09.010

M. F. Hochella-jr, G. E. Brown, and . Jr, Aspects of silicate surface and bulk structure analysis using X-ray photoelectron spectroscopy (XPS), Geochimica et Cosmochimica Acta, vol.52, issue.6, pp.1641-1648, 1988.
DOI : 10.1016/0016-7037(88)90232-3

V. P. Zakaznova-herzog, H. W. Nesbitt, G. M. Bancroft, and J. S. Tse, High resolution core and valence band XPS spectra of non-conductor pyroxenes, Surface Science, vol.600, issue.16, pp.600-3175, 2006.
DOI : 10.1016/j.susc.2006.06.012

J. Antelo, S. Fiol, C. Pérez, S. Mariño, F. Arce et al., Analysis of phosphate adsorption onto ferrihydrite using the CD-MUSIC model, Journal of Colloid and Interface Science, vol.347, issue.1, pp.112-119, 2010.
DOI : 10.1016/j.jcis.2010.03.020

K. Hanna, B. Rusch, L. Lassabatere, A. Hofmann, and B. Humbert, Reactive transport of gentisic acid in a hematite-coated sand column: Experimental study and modeling, Geochimica et Cosmochimica Acta, vol.74, issue.12, pp.3351-3366, 2010.
DOI : 10.1016/j.gca.2010.03.022

URL : https://hal.archives-ouvertes.fr/hal-00509082

B. Rusch, K. Hanna, and B. Humbert, Sorption and Transport of Salicylate in a Porous Heterogeneous Medium of Silica Quartz and Goethite, Environmental Science & Technology, vol.44, issue.7, pp.44-2447, 2010.
DOI : 10.1021/es903517y

URL : https://hal.archives-ouvertes.fr/hal-00477320

B. Rusch, K. Hanna, and B. Humbert, Coating of quartz silica with iron oxides: Characterization and surface reactivity of iron coating phases, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.353, issue.2-3
DOI : 10.1016/j.colsurfa.2009.11.009

URL : https://hal.archives-ouvertes.fr/hal-00468405

I. R. Willett, C. J. Chartres, and T. T. Nguyen, Migration of phosphate into aggregated particles of ferrihydrite, Journal of Soil Science, vol.21, issue.2, pp.275-282, 1988.
DOI : 10.1111/j.1365-2389.1988.tb01214.x

Y. S. Ho and G. Mckay, Pseudo-second order model for sorption processes, Process Biochemistry, vol.34, issue.5, pp.451-465, 1999.
DOI : 10.1016/S0032-9592(98)00112-5

X. M. Wang, F. Liu, W. F. Tan, W. Li, X. H. Feng et al., Characteristics of Phosphate Adsorption-Desorption Onto Ferrihydrite, Soil Science, vol.178, issue.1, pp.178-179, 2013.
DOI : 10.1097/SS.0b013e31828683f8

R. Chitrakar, S. Tezuka, A. Sonoda, K. Sakane, K. Ooi et al., Phosphate adsorption on synthetic goethite and akaganeite, Journal of Colloid and Interface Science, vol.298, issue.2, pp.602-608, 2006.
DOI : 10.1016/j.jcis.2005.12.054

J. Kim, W. Li, B. L. Philips, and C. P. Grey, Phosphate adsorption on the iron oxyhydroxides goethite (??-FeOOH), akaganeite (??-FeOOH), and lepidocrocite (??-FeOOH): a 31P NMR Study, Energy & Environmental Science, vol.31, issue.10, pp.4298-4305, 2011.
DOI : 10.1039/c1ee02093e

T. Hiemstra and W. H. Van-riemsdijk, On the relationship between charge distribution, surface hydration, and the structure of the interface of metal hydroxides, Journal of Colloid and Interface Science, vol.301, issue.1, pp.1-18, 2006.
DOI : 10.1016/j.jcis.2006.05.008

J. A. Davis, J. A. Coston, D. B. Kent, and C. C. Fuller, Application of the Surface Complexation Concept to Complex Mineral Assemblages, Environmental Science & Technology, vol.32, issue.19, pp.32-2820, 1998.
DOI : 10.1021/es980312q

C. J. Tadanier and M. J. Eick, Formulating the Charge-distribution Multisite Surface Complexation Model Using FITEQL, Soil Science Society of America Journal, vol.66, issue.5, pp.1505-1517, 2002.
DOI : 10.2136/sssaj2002.1505

T. Hiemstra, J. C. De-wit, and W. H. Van-riemsdijk, Multisite proton adsorption modeling at the solid/solution interface of (hydr)oxides: A new approach, Journal of Colloid and Interface Science, vol.133, issue.1, pp.105-117, 1989.
DOI : 10.1016/0021-9797(89)90285-3

T. Hiemstra and W. H. Van-riemsdijk, A Surface Structural Approach to Ion Adsorption: The Charge Distribution (CD) Model, Journal of Colloid and Interface Science, vol.179, issue.2, pp.488-508, 1996.
DOI : 10.1006/jcis.1996.0242

D. L. Parkhurst and C. A. Appelo, User's guide to PHREEQC (Version 2)--A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations, Water-resources investigations report, pp.99-4259, 1999.

Y. Arai and D. L. Sparks, ATR???FTIR Spectroscopic Investigation on Phosphate Adsorption Mechanisms at the Ferrihydrite???Water Interface, Journal of Colloid and Interface Science, vol.241, issue.2, pp.317-326, 2001.
DOI : 10.1006/jcis.2001.7773

B. C. Barja, M. I. Tejedor-tejedor, and M. A. Anderson, Complexation of Methylphosphonic Acid with the Surface of Goethite Particles in Aqueous Solution, Langmuir, vol.15, issue.7, pp.2316-2321, 1999.
DOI : 10.1021/la980540y

C. Luengo, M. Brigante, J. Antelo, and M. Avena, Kinetics of phosphate adsorption on goethite: Comparing batch adsorption and ATR-IR measurements, Journal of Colloid and Interface Science, vol.300, issue.2, pp.511-518, 2006.
DOI : 10.1016/j.jcis.2006.04.015

N. Khare, J. D. Martin, and D. Hesterberg, Phosphate bonding configuration on ferrihydrite based on molecular orbital calculations and XANES fingerprinting, Geochimica et Cosmochimica Acta, vol.71, issue.18, pp.4405-4415, 2007.
DOI : 10.1016/j.gca.2007.07.008

K. Hanna and J. F. Boily, Sorption of Two Naphthoic Acids to Goethite Surface under Flow through Conditions, Environmental Science & Technology, vol.44, issue.23, pp.8863-8869, 2010.
DOI : 10.1021/es102903n

URL : https://hal.archives-ouvertes.fr/hal-00919729

M. T. Van-genuchten and P. J. Wierenga, Mass transfer studies in sorbing porous media I. Analytical solutions, Soil Sci. Soc. Am. J, pp.40-473, 1976.

K. Hanna, L. Lassabatere, and B. Bechet, Transport of two naphthoic acids and salicylic acid in soil: Experimental study and empirical modeling, Water Research, vol.46, issue.14, pp.4457-4467, 2012.
DOI : 10.1016/j.watres.2012.04.037

URL : https://hal.archives-ouvertes.fr/halsde-00766621

M. Stachowicz, T. Hiemstra, and W. H. Van-riemsdijk, Multi-competitive interaction of As(III) and As(V) oxyanions with Ca2+, Mg2+, PO3???4, and CO2???3 ions on goethite, Journal of Colloid and Interface Science, vol.320, issue.2, pp.400-414, 2008.
DOI : 10.1016/j.jcis.2008.01.007

R. P. Rietra, T. Hiemstra, and W. H. Van-riemsdijk, Interaction between Calcium and Phosphate Adsorption on Goethite, Environmental Science & Technology, vol.35, issue.16, pp.3369-3374, 2001.
DOI : 10.1021/es000210b