C. Mhz, 1; HRMS (ESI, m/z): Calcd. for C13H21NO4Na: 278.1363, found [M+Na] + : 278.1363; HPLC analysis (Chiralpak IA column, heptane/2-propanol = 97/3, flow rate = 1 mL/min, wavelength = 220 nm): Rt =21, p.60

. Hz, 0; HRMS (ESI, m/z): Calcd. for C19H24NO4FNa: 372.1587, found [M+Na] + : 372.1585; HPLC analysis (Chiralpak IA column, heptane/2- propanol = 95/5, flow rate = 1 mL/min, wavelength = 220 nm): Rt =15, p.2642

B. H. Lipshutz, Five-membered heteroaromatic rings as intermediates in organic synthesis, Chemical Reviews, vol.86, issue.5, pp.795-819, 1986.
DOI : 10.1021/cr00075a005

C. Paolucci and G. Rosini, Approach to a better understanding and modeling of (S)-dihydrofuran-2-yl, (S)-tetrahydrofuran-2-yl-, and furan-2-yl-??-dialkylaminoethanol ligands for enantioselective alkylation, Tetrahedron: Asymmetry, vol.18, issue.24, pp.2923-2946, 2008.
DOI : 10.1016/j.tetasy.2007.11.034

W. Zhou, Z. Lu, Y. Xu, L. Liao, and Z. Wang, Synthesis of optically active ??-furfuryl amine derivatives and application to the asymmetric syntheses, Tetrahedron, vol.55, issue.41, pp.11959-11983, 1999.
DOI : 10.1016/S0040-4020(99)00669-9

O. Achmatowicz, P. Bukowski, B. Szechnev, Z. Zwierzchowska, and A. Zamojski, Synthesis of methyl 2,3-dideoxy-DL-alk-2-enopyranosides from furan compounds, Tetrahedron, vol.27, issue.10, pp.1973-1996, 1971.
DOI : 10.1016/S0040-4020(01)98229-8

A. S. Demir, O. Sesenoglu, D. Uelkue, C. Ar?c?, M. L. Bushey et al., Novel Enantioselective Synthesis of Both Enantiomers of Furan-2-yl Amines and Amino Acids, Helvetica Chimica Acta, vol.47, issue.1, pp.91-105, 1998.
DOI : 10.1002/hlca.200390022

N. Irako, Y. Hamada, T. Shioiri, W. S. Zhou, Z. H. Lu et al., A New Asymmetric Synthesis of (S)-Dolaphenine and Its Heteroaromatic Congeners Utilizing (+)-2-Hydroxy-3-pinanone and (???)-3-Hydroxy-2-caranone as Chiral Auxiliaries, Tetrahedron, vol.51, issue.46, pp.12731-12744, 1991.
DOI : 10.1016/0040-4020(95)00828-V

R. Alfaro, F. Yuste, B. Ortiz, R. Sanchez-obregon, J. L. Garc?a-ruano et al., ??-Amino vinyl sulfoxides in asymmetric synthesis. Synthesis of optically pure ??-substituted ??-amino nitriles, Tetrahedron, vol.65, issue.1, pp.357-363, 2009.
DOI : 10.1016/j.tet.2008.10.037

K. Takai, K. Nitta, and K. D. Utimoto, Simple and selective method for aldehydes (RCHO) .fwdarw. (E)-haloalkenes (RCH:CHX) conversion by means of a haloform-chromous chloride system, Journal of the American Chemical Society, vol.108, issue.23, pp.7408-7410, 1986.
DOI : 10.1021/ja00283a046

Y. Fu, J. Bieschke, J. W. Kelly, J. Kaltenbronn, and . Hudspeth, Olefin Dipeptide Isostere Incorporation into a Polypeptide Backbone Enables Hydrogen Bond Perturbation:?? Probing the Requirements for Alzheimer's Amyloidogenesis, Journal of the American Chemical Society, vol.127, issue.44, pp.15366-15367, 2005.
DOI : 10.1021/ja0551382

D. 'aniello, F. Mann, A. Schoenfelder, A. Taddei, and M. , Stereoconvergent synthesis of (2S,3S,8S,9S,4E,6E)-N-Boc-ADDA starting from (S)-serine and (S)-phenyllactic acid, Tetrahedron, vol.53, issue.4, pp.1447-1456, 1997.
DOI : 10.1016/S0040-4020(96)01056-3

K. H. Nguyen, S. Tomasi, M. Le-roch, L. Toupet, J. Renault et al., Gold-Mediated Synthesis and Functionalization of Chiral Halopyridones, The Journal of Organic Chemistry, vol.78, issue.16, pp.7809-7815, 2013.
DOI : 10.1021/jo400827b

URL : https://hal.archives-ouvertes.fr/hal-00866844

N. Miyaura, A. Suzuki, and A. Suzuki, Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds, Chemical Reviews, vol.95, issue.7, pp.2457-2483, 1995.
DOI : 10.1021/cr00039a007

R. F. Heck, Acylation, methylation, and carboxyalkylation of olefins by Group VIII metal derivatives, Journal of the American Chemical Society, vol.90, issue.20, pp.5518-5526, 1968.
DOI : 10.1021/ja01022a034

K. Sonogashira, Y. Tohda, and N. Hagihara, A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines, Tetrahedron Letters, vol.16, issue.50, pp.4467-4470, 1975.
DOI : 10.1016/S0040-4039(00)91094-3

A. S. Guram, R. A. Rennels, S. L. Buchwald, J. Louie, and J. F. Hartwig, A Simple Catalytic Method for the Conversion of Aryl Bromides to Arylamines, Angewandte Chemie International Edition in English, vol.34, issue.12, pp.1348-1350, 1995.
DOI : 10.1002/anie.199513481