57 (d, 1 J P-C = 48.3 Hz, C ), 148.69 (d, 2 J P-C = 14, pp.89-176 ,
13% yield) and two inseparable isomers of formula [Os 3 (CO) 10 (? 1 -PC 15 H 14 N) 2 ] (4) (28% yield) Spectral data for 3 13 C{ 1 H} NMR (500 MHz, CDCl 3 ): = 13 (s) Spectral data for, cyclohexane): 2108 w w. 1 H NMR (500 MHz, CDCl 3 ): = 2.17 (m, 2H, H ), 2.93 (m, 2H, H ), 7.48 (m, 10H cyclohexane): 2088 w w. 1 H NMR (500 MHz, CDCl 3 ): = 2.15 (m, 2H, H ), 2.92 (m, 2H, H ), pp.84-17147, 1957. ,
61 (d, 1 J P-C = 2781 (d, 3 J P-C = 17.8 Hz, C ? ), 129.06 (d, 3 J P-C = 10.4 Hz, m-C Ph ), pp.17-31 ,
Metal clusters. 21. Synthesis of rhodium phosphite clusters, Journal of the American Chemical Society, vol.101, issue.17, p.4878, 1979. ,
DOI : 10.1021/ja00511a016
A new member of the (HRhL2)x cluster class: [(.mu.-H)Rh(1,5-cyclooctadiene)]4, Organometallics, vol.1, issue.9, p.1256, 1982. ,
DOI : 10.1021/om00069a034
Addition reactions of a polynuclear osmium hydrido compound leading to associative carbonyl substitution and catalytic alkene isomerisation, Journal of Organometallic Chemistry, vol.114, issue.3, p.313, 1976. ,
DOI : 10.1016/S0022-328X(00)87289-7
-triosmium, Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, vol.35, issue.9, p.2210, 1979. ,
DOI : 10.1107/S0567740879008827
URL : https://hal.archives-ouvertes.fr/hal-00186600
Nonrigidity in the isomers of osmium cluster Os3(.mu.-H)2(CO)9(CNBu-tert). Structure of the green isomer, Organometallics, vol.9, issue.1, p.45, 1990. ,
DOI : 10.1021/om00115a008
Isocyanide insertion reactions and their role in the cluster-catalyzed hydrogenation of isocyanide molecules, Journal of the American Chemical Society, vol.101, issue.10, p.2579, 1979. ,
DOI : 10.1021/ja00504a013
Insertion of a phospholide unit into a metal???metal bond: Synthesis and X-ray structure of [Ru3(CO)9(??:??1:??5-PC4H2Me2)(??1-C6H5)], Inorganica Chimica Acta, vol.392, p.241, 2012. ,
DOI : 10.1016/j.ica.2012.01.033
Structural studies on polynuclear osmium carbonyl hydrides. 3. Crystal structure and molecular geometry of decacarbonyldihydro(triphenylphosphine)triosmium including direct location of both terminal and .mu.2-bridging hydride ligands, Inorganic Chemistry, vol.16, issue.9, p.2397, 1977. ,
DOI : 10.1021/ic50175a047
Catalytic Hydrogenation by Triruthenium Clusters: A Mechanistic Study with Parahydrogen-Induced Polarization, Chemistry - A European Journal, vol.9, issue.5, p.1045, 2003. ,
DOI : 10.1002/chem.200390098
Fluxional behaviour of the clusters Os3(??-H)2(CO)9(L), L = PMe2Ph, PMe3, PiPr3, P(o-tolyl)3 and PPh(1-naphthyl)2. Crystal structure of Os3(??-H)2(CO)9(PiPr3), Journal of Organometallic Chemistry, vol.394, issue.1-3, p.515, 1990. ,
DOI : 10.1016/0022-328X(90)87252-9
Nonrigidity in Os3(CO)12-x[P(OMe)3]x (x = 1-4), Organometallics, vol.6, issue.11, p.2437, 1987. ,
DOI : 10.1021/om00154a027
Phosphole-Containing ??-Conjugated Systems: From Model Molecules to Polymer Films on Electrodes, Chemistry - A European Journal, vol.31, issue.19, p.4222, 2001. ,
DOI : 10.1002/1521-3765(20011001)7:19<4222::AID-CHEM4222>3.0.CO;2-3
Syntheses, characterization, and properties of palladium(II) complexes containing bidentate phosphine-nitrile or phosphine-imidate ligands, Inorganic Chemistry, vol.24, issue.15, p.2344, 1985. ,
DOI : 10.1021/ic00209a005