Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines

İsmail Özdemir (1) , Serpil Demir Düşünceli , Nazan Kaloğlu , Mathieu Achard (2) , Christian Bruneau (2)

1 Inönü University
2 ISCR - Institut des Sciences Chimiques de Rennes

The novel ruthenium N-Heterocyclic carbene complexes are synthesized, and characterized by studying its 1H, 13C, elemental analysis, and X-ray. These complexes have been reported as promising catalyst for β C–H bond functionalization of tertiary cyclic amines through hydrogen autotransfers in the presence of external acidic additive. The new catalytic products were characterized by 1H NMR, 13C NMR spectroscopic methods

Mots clés: Catalysis; Cyclic amine; N-Heterocyclic carbene; ruthenium

Domaines: Chimie

İsmail Özdemir, Serpil Demir Düşünceli, Nazan Kaloğlu, Mathieu Achard, Christian Bruneau. Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines. Journal of Organometallic Chemistry, 2015, 799–800, pp.311--315. ⟨10.1016/j.jorganchem.2015.10.011⟩. ⟨hal-01220885⟩