Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me2I2TTF]2Br - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2016

Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me2I2TTF]2Br

Résumé

The Z and E isomers of the iodinated TTF derivative (Z,E)-Me2I2-TTF co-crystallize in a mixed-valence salt with Br(-) anions, and are segregated into Z and E stacks, each of them with a different charge localization pattern, which also revealed charge-assisted halogen bonding

Domaines

Chimie

Dates et versions

hal-01224513 , version 1 (04-11-2015)

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Citer

Olivier Jeannin, Enric Canadell, Pascale Auban-Senzier, Marc Fourmigué. Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me2I2TTF]2Br. Chemical Communications, 2016, 52 (2), pp.308-311. ⟨10.1039/c5cc08176a⟩. ⟨hal-01224513⟩
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