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Spontaneous Tl(I)-to-Tl(III) oxidation in dynamic heterobimetallic Hg(II)/Tl(I) porphyrin complexes

Abstract : Strapped heterobimetallic Hg(II)/Tl(I) porphyrin complexes, with both metal ions bridged by the N-core in a dynamic way, undergo spontaneous Tl(I)-to-Tl(III) oxidn. leading to a mono-Tl(III) complex and a mixed valence Tl(I)/Tl(III) bimetallic complex. It provides a new opportunity to tune metal ion translocations in bimetallic porphyrin systems.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01231147
Contributor : Laurent Jonchère <>
Submitted on : Thursday, November 19, 2015 - 3:46:19 PM
Last modification on : Thursday, March 5, 2020 - 2:05:56 PM

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Victoria Ndoyom, Luca Fusaro, Thierry Roisnel, Stephane Le Gac, Bernard Boitrel. Spontaneous Tl(I)-to-Tl(III) oxidation in dynamic heterobimetallic Hg(II)/Tl(I) porphyrin complexes. Chemical Communications, Royal Society of Chemistry, 2016, 52 (3), pp.517-520. ⟨10.1039/C5CC07828H⟩. ⟨hal-01231147⟩

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