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Journal articles
Spontaneous Tl(I)-to-Tl(III) oxidation in dynamic heterobimetallic Hg(II)/Tl(I) porphyrin complexes
Abstract : Strapped heterobimetallic Hg(II)/Tl(I) porphyrin complexes, with both metal ions bridged by the N-core in a dynamic way, undergo spontaneous Tl(I)-to-Tl(III) oxidn. leading to a mono-Tl(III) complex and a mixed valence Tl(I)/Tl(III) bimetallic complex. It provides a new opportunity to tune metal ion translocations in bimetallic porphyrin systems.
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01231147
Contributor : Laurent Jonchère <>
Submitted on : Thursday, November 19, 2015 - 3:46:19 PM
Last modification on : Thursday, February 11, 2021 - 9:12:13 AM
Contributor : Laurent Jonchère <>
Submitted on : Thursday, November 19, 2015 - 3:46:19 PM
Last modification on : Thursday, February 11, 2021 - 9:12:13 AM