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Two-photon Absorption Engineering of 5-(Fluorenyl)-1,10-phenanthroline-based Ru(II) Complexes

Abstract : This study deals with the fine tuning of the photophysical characteristics, and especially two-photon absorption (2PA) properties, of several homo- and heteroleptic ruthenium(II) complexes involving 5-substituted-1,10-phenanthroline ligands. The 2PA spectra of the complexes were determined in the 700-930 nm range by investigating their two-photon excited luminescence (2PEL). Structure - linear and nonlinear optical properties correlations are discussed, and potential applications (therapy and optical power limiting in the near infrared) can be anticipated.
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Olivier Mongin, Mickael Four, Sylviane Chevreux, Mireille Blanchard-Desce, Gilles Lemercier. Two-photon Absorption Engineering of 5-(Fluorenyl)-1,10-phenanthroline-based Ru(II) Complexes. CHIMIA, Schweizerische Chemische Gesellschaft, 2015, 69 (11), pp.666--669. ⟨10.2533/chimia.2015.666⟩. ⟨hal-01254816⟩

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