Global analysis of the high temperature infrared emission spectrum of (12)CH4 in the dyad (ν2/ν4) region - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Journal of Chemical Physics Année : 2016

Global analysis of the high temperature infrared emission spectrum of (12)CH4 in the dyad (ν2/ν4) region

Résumé

We report new assignments of vibration-rotation line positions of methane ((12)CH4) in the so-called dyad (ν2/ν4) region (1100-1500 cm(-1)), and the resulting update of the vibration-rotation effective model of methane, previously reported by Nikitin et al. [Phys. Chem. Chem. Phys. 15, 10071 (2013)], up to and including the tetradecad. High resolution (0.01 cm(-1)) emission spectra of methane have been recorded up to about 1400 K using the high-enthalpy source developed at Institut de Physique de Rennes associated with the Fourier transform spectrometer of the SOLEIL synchrotron facility (AILES beamline). Analysis of these spectra allowed extending rotational assignments in the well-known cold band (dyad-ground state (GS)) and related hot bands in the pentad-dyad system (3000 cm(-1)) up to Jmax = 30 and 29, respectively. In addition, 8512 new transitions belonging to the octad-pentad (up to J = 28) and tetradecad-octad (up to J = 21) hot band systems were successfully identified. As a result, the MeCaSDa database of methane was significantly improved. The line positions assigned in this work, together with the information available in the literature, were fitted using 1096 effective parameters with a dimensionless standard deviation σ = 2.09. The root mean square deviations dRMS are 3.60 × 10(-3) cm(-1) for dyad-GS cold band, 4.47 ×10(-3) cm(-1) for the pentad-dyad, 5.43 × 10(-3) cm(-1) for the octad-pentad, and 4.70 × 10(-3) cm(-1) for the tetradecad-octad hot bands. The resulting new line list will contribute to improve opacity and radiative transfer models for hot atmospheres, such as those of hot-Jupiter type exoplanets

Dates et versions

hal-01259513 , version 1 (20-01-2016)

Identifiants

Citer

Badr Amyay, Maud Louviot, Olivier Pirali, Robert Georges, Jean Vander Auwera, et al.. Global analysis of the high temperature infrared emission spectrum of (12)CH4 in the dyad (ν2/ν4) region. Journal of Chemical Physics, 2016, 144 (2), pp.024312. ⟨10.1063/1.4939521⟩. ⟨hal-01259513⟩
170 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More