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Synthesis and chemical reactivity of new zinc porphyrin diazoacetates catalyzed by ruthenium and iron porphyrins

Abstract : Zinc porphyrin diazoacetates were synthesized from the corresponding bromoacetates by treatment with N,N’-ditosylhydrazine in ∼70% yield. The transfer of carbenoids derived from the porphyrin diazo compounds catalyzed by metalloporphyrins (Ru,Fe) undergoes dimerization, cyclopropanation, N-H and S-H insertion reactions, respectively
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Submitted on : Friday, April 22, 2016 - 2:57:11 PM
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Daniel Carrié, Hassan Srour, Paul Le Maux, Gérard Simonneaux. Synthesis and chemical reactivity of new zinc porphyrin diazoacetates catalyzed by ruthenium and iron porphyrins. Tetrahedron Letters, Elsevier, 2016, 57 (10), pp. 1179-1182. ⟨10.1016/j.tetlet.2016.02.010⟩. ⟨hal-01269738⟩

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