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μ1,1-R-phenylcyanamido bridges as a new safe synthetic strategy for ferromagnetic molecular clusters

Abstract : The reaction of Ni(NO3)2·6H2O with di-2-pyridyl ketone, (py)2CO, and the R-phenylcyanamides 4Cl-3CF3-PhHNCN and 4F-3CF3-PhHNCN in CH3OH or CH3CH2OH allows the isolation of the tetranuclear compounds [(Ni4(μ-py2COOCH3)2(μ3-py2COOH)2(μ1,1-4Cl-3CF3-PhNCN)2(4Cl-3CF3-PhNCN)2]·CH3OH (), [(Ni4(μ-py2COOCH2CH3)2(μ3-py2COOH)2(μ1,1-4Cl-3CF3-PhNCN)2(4Cl-3CF3-PhNCN)2]·2EtOH () and [(Ni4(μ-py2COOCH3)2(μ3-py2COOH)2(μ1,1-4F-3CF3-PhNCN)2(4F-3CF3-PhNCN)2]·4CH3OH (). \(py)2C(OH)O\(-) and \(py)2C(OR)O\(-) are the monoanions of the gem-diol and hemiketal (R = CH3, CH2CH3) forms of (py)2CO. X-ray diffraction analysis reveals defective double-cubane tetrameric entities in which the Ni(ii) atoms are linked by μ1,1-R-phenylcyanamido bridges and two kinds of O-bridges. The molar magnetic susceptibility measurements of in the 2-300 K range indicate bulk ferromagnetic coupling
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01282460
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Submitted on : Thursday, March 3, 2016 - 4:43:43 PM
Last modification on : Friday, July 10, 2020 - 4:03:16 PM

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Saskia Speed, Berta Casanovas, Ramon Vicente. μ1,1-R-phenylcyanamido bridges as a new safe synthetic strategy for ferromagnetic molecular clusters. Dalton Transactions, Royal Society of Chemistry, 2016, 45 (12), pp.5395-5403. ⟨10.1039/c5dt04306a⟩. ⟨hal-01282460⟩

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