H. W. Gschwend, H. R. Rodriguez, . Org, and . React, 26, 1; b) P. Beak, V. Snieckus, Acc. Chem. Res. Chem. Rev, vol.15, issue.90, p.879, 1979.

I. '. Schlosser, Organometallics in Synthesis, 2002.

M. Uchiyama, T. Miyoshi, Y. Kajihara, T. Sakamoto, Y. Otani et al., Generation of Functionalized Asymmetric Benzynes with TMP-Zincates. Effects of Ligands on Selectivity and Reactivity of Zincates, Journal of the American Chemical Society, vol.124, issue.29, p.8514, 2002.
DOI : 10.1021/ja0202199

T. D. Krizan and J. C. Martin, In situ trapping of ortho lithiated benzenes containing electrophilic directing groups, Journal of the American Chemical Society, vol.105, issue.19, p.6155, 1983.
DOI : 10.1021/ja00357a034

T. Klis´, S. Klis´, J. Lulin´skilulin´ski, and . Serwatowski, Remote-Substituent-Directed Metalations of Arenes, Current Organic Chemistry, vol.12, issue.17, p.1479, 2008.
DOI : 10.2174/138527208786241475

E. Castagnetti and M. Schlosser, The Trifluoromethoxy Group: A Long-Range Electron-Withdrawing Substituent, Chemistry - A European Journal, vol.136, issue.4, p.799, 2002.
DOI : 10.1002/1521-3765(20020215)8:4<799::AID-CHEM799>3.0.CO;2-6

). F. Faigl, E. Marzi, and M. Schlosser, Enhancement of Benzylic Basicity by a Fluorine Substituent at thepara-Position: A Case of Lone Pair/Lone Pair Repulsion, Chemistry - A European Journal, vol.6, issue.5, p.771, 1251.
DOI : 10.1002/(SICI)1521-3765(20000303)6:5<771::AID-CHEM771>3.0.CO;2-G

F. Mongin, M. Schlosser, and T. Lett, [14] 2-Chlorobenzoic acid is isolated in 21% yield using LiTMP (1 equiv.) at ?75 °C for 2 hours equiv.) at ?75 °C for 6 hours. [15] 2-Bromophenyltrimethylsilane can be obtained in about 40% yield, 43% yield using LiTMP (2 equiv.) at ?75 °C for 2 hours, 45% yield using LiTMP, 1559.

S. Lulin´skilulin´ski and J. Serwatowski, Bromine as the Ortho-Directing Group in the Aromatic Metalation/Silylation of Substituted Bromobenzenes, The Journal of Organic Chemistry, vol.68, issue.24, p.9384, 2003.
DOI : 10.1021/jo034790h

M. Schlosser, Parametrization of Substituents: Effects of Fluorine and Other Heteroatoms on OH, NH, and CH Acidities, Angewandte Chemie International Edition, vol.37, issue.11, p.1496, 1998.
DOI : 10.1002/(SICI)1521-3773(19980619)37:11<1496::AID-ANIE1496>3.0.CO;2-U