F. Schreiber, Structure and growth of self-assembling monolayers, Progress in Surface Science, vol.65, issue.5-8, p.151, 2000.
DOI : 10.1016/S0079-6816(00)00024-1

A. Badia, R. Lennox, and L. Reven, A Dynamic View of Self-Assembled Monolayers, Accounts of Chemical Research, vol.33, issue.7, p.475, 2000.
DOI : 10.1021/ar9702841

H. B. Akkerman and B. De-boer, Electrical conduction through single molecules and self-assembled monolayers, Journal of Physics: Condensed Matter, vol.20, issue.1, p.13001, 2008.
DOI : 10.1088/0953-8984/20/01/013001

A. Salomon, D. Cahen, S. M. Lindsay, J. Tomfohr, V. Engelkes et al., Comparison of Electronic Transport Measurements on Organic Molecules, Advanced Materials, vol.15, issue.22, p.1881, 2003.
DOI : 10.1002/adma.200306091

D. Vuillaume, Molecular-scale electronics, Comptes Rendus Physique, vol.9, issue.1, p.78, 2008.
DOI : 10.1016/j.crhy.2007.10.014
URL : https://hal.archives-ouvertes.fr/hal-00146171

A. Vilan, O. Yaffe, A. Biller, A. Salomon, A. Kahn et al., Molecules on Si: Electronics with Chemistry, Advanced Materials, vol.102, issue.2, p.140, 2010.
DOI : 10.1002/adma.200901834

A. B. Fadjie-djomkam, S. Ababou-girard, R. Hiremath, C. Herrier, B. Fabre et al., Temperature dependence of current density and admittance in metal-insulator-semiconductor junctions with molecular insulator, Journal of Applied Physics, vol.110, issue.8, p.83708, 2011.
DOI : 10.1063/1.3651401
URL : https://hal.archives-ouvertes.fr/hal-00658315

Y. Selzer, A. Salomon, and D. Cahen, The Importance of Chemical Bonding to the Contact for Tunneling through Alkyl Chains, The Journal of Physical Chemistry B, vol.106, issue.40, p.10432, 2002.
DOI : 10.1021/jp026324m

A. Salomon, H. Shpaisman, O. Seitz, T. Böcking, and D. Cahen, Temperature-Dependent Electronic Transport through Alkyl Chain Monolayers:??? Evidence for a Molecular Signature, The Journal of Physical Chemistry C, vol.112, issue.10, p.3969, 2008.
DOI : 10.1021/jp710985b

H. Shpaisman, O. Seitz, O. Yaffe, K. Roodenko, L. Scheres et al., Structure Matters: Correlating temperature dependent electrical transport through alkyl monolayers with vibrational and photoelectron spectroscopies, Chem. Sci., vol.101, issue.3, p.851, 2012.
DOI : 10.1039/C1SC00639H

A. B. Fadjie-djomkam, S. Ababou-girard, and C. Godet, Barrier height distribution and dipolar relaxation in metal-insulator-semiconductor junctions with molecular insulator: Ageing effects, Journal of Applied Physics, vol.112, issue.11, p.113701, 2012.
DOI : 10.1063/1.4767121
URL : https://hal.archives-ouvertes.fr/hal-01121392

J. Hautman and M. Klein, Molecular dynamics simulation of the effects of temperature on a dense monolayer of long???chain molecules, The Journal of Chemical Physics, vol.93, issue.10, p.7483, 1990.
DOI : 10.1063/1.459423

J. Hautman, J. P. Bareman, W. Mar, and M. Klein, Molecular dynamics investigations of self-assembled monolayers, Journal of the Chemical Society, Faraday Transactions, vol.87, issue.13, p.2031, 1991.
DOI : 10.1039/ft9918702031

S. J. Klatte and T. Beck, Molecular dynamics of tethered alkanes: temperature-dependent behavior in a high-density chromatographic system, The Journal of Physical Chemistry, vol.97, issue.21, p.5727, 1993.
DOI : 10.1021/j100123a044

L. Zhang, K. Wesley, and S. Jiang, Molecular Simulation Study of Alkyl Monolayers on Si(111), Langmuir, vol.17, issue.20, p.6275, 2001.
DOI : 10.1021/la0106337

S. Singh, J. Wegmann, K. Albert, and K. Muller, Alkyl Modified Silica Gels, The Journal of Physical Chemistry B, vol.106, issue.4, p.878, 2002.
DOI : 10.1021/jp012979w

R. Boyd, The energetics of kinks in polyethylene, Journal of Polymer Science: Polymer Physics Edition, vol.13, issue.12, p.2345, 1975.
DOI : 10.1002/pol.1975.180131209

S. Pleutin, N. Clement, D. Guerin, and D. Vuillaume, Molecular relaxation dynamics in organic monolayer junctions, Physical Review B, vol.82, issue.12, p.125436, 2010.
DOI : 10.1103/PhysRevB.82.125436
URL : https://hal.archives-ouvertes.fr/hal-00548968

N. Clement, S. Pleutin, D. Guerin, and D. Vuillaume, Relaxation dynamics in covalently bonded organic monolayers on silicon, Physical Review B, vol.82, issue.3, p.35404, 2010.
DOI : 10.1103/PhysRevB.82.035404
URL : https://hal.archives-ouvertes.fr/hal-00548973

C. Godet, A. B. Fadjie-djomkam, S. Ababou-girard, S. Tricot, P. Turban et al., Dynamics of Substituted Alkyl Monolayers Covalently Bonded to Silicon: A Broadband Admittance Spectroscopy Study, The Journal of Physical Chemistry C, vol.118, issue.13, p.6773, 2014.
DOI : 10.1021/jp411937t
URL : https://hal.archives-ouvertes.fr/hal-01151707

C. Godet, Entropy effects in the collective dynamic behavior of alkyl monolayers tethered to Si(111), Beilstein Journal of Nanotechnology, vol.6, p.583, 2015.
DOI : 10.3762/bjnano.6.60
URL : https://hal.archives-ouvertes.fr/hal-01121389

A. Vassilikou-dova and I. Kalogeras, Thermal analysis of Polymers: Fundamentals and Applications, p.497, 2009.

D. B. Knorr, P. Widjaja, O. Acton, and R. Overney, Molecular friction dissipation and mode coupling in organic monolayers and polymer films, The Journal of Chemical Physics, vol.134, issue.10, p.104502, 2011.
DOI : 10.1063/1.3556668

S. Cordier, B. Fabre, Y. Molard, A. B. Fadjie-djomkam, N. Tournerie et al., Cluster Cores Monolayers on Modified n- and p-Type Si(111) Surfaces: Effect of Coverage on Electronic Properties, The Journal of Physical Chemistry C, vol.114, issue.43, p.18622, 2010.
DOI : 10.1021/jp1071007

H. Asanuma, G. Lopinski, and H. Yu, Kinetic Control of the Photochemical Reactivity of Hydrogen-Terminated Silicon with Bifunctional Molecules, Langmuir, vol.21, issue.11, pp.5013-5018, 2005.
DOI : 10.1021/la0474969

C. J. Powell and A. Jablonski, Electron Inelastic-Mean-Free-Path, Database version 1, 2000.

X. Wallart, H. De-villeneuve, C. Allongue, and P. , Truly Quantitative XPS Characterization of Organic Monolayers on Silicon: Study of Alkyl and Alkoxy Monolayers on H???Si(111), Journal of the American Chemical Society, vol.127, issue.21, p.7871, 2005.
DOI : 10.1021/ja0430797
URL : https://hal.archives-ouvertes.fr/hal-00125385

L. A. Dissado and R. Hill, Non-exponential decay in dielectrics and dynamics of correlated systems, Nature, vol.64, issue.2, p.685, 1979.
DOI : 10.1088/0034-4885/41/4/003

V. Naik and S. Vasudevan, Conformational Dynamics in Alkyl Chains of an Anchored Bilayer: A Molecular Dynamics Study, The Journal of Physical Chemistry C, vol.113, issue.20, p.8806, 2009.
DOI : 10.1021/jp810674c

J. B. Klauda, B. R. Brooks, A. D. Mackerell, R. Venable, and R. W. Pastor, An ab Initio Study on the Torsional Surface of Alkanes and Its Effect on Molecular Simulations of Alkanes and a DPPC Bilayer, The Journal of Physical Chemistry B, vol.109, issue.11, p.5300, 2005.
DOI : 10.1021/jp0468096

G. Smith and R. Jaffe, -Alkanes, The Journal of Physical Chemistry, vol.100, issue.48, p.18718, 1996.
DOI : 10.1021/jp960413f
URL : https://hal.archives-ouvertes.fr/hal-00309731

N. J. Heaton, R. Benavente, E. Perez, A. Bello, and J. Perena, The ?? relaxation in polymers containing ether linkages: conformational dynamics in the amorphous phase for a series of polybibenzoates containing oxyethylene spacers, Polymer, vol.37, issue.17, p.3791, 1996.
DOI : 10.1016/0032-3861(96)00228-5

R. Boyd, Relaxation processes in crystalline polymers: molecular interpretation ??? a review, Polymer, vol.26, issue.8, p.1123, 1985.
DOI : 10.1016/0032-3861(85)90240-X

S. Glasstone, K. J. Laidler, and H. Eyring, The theory of molecular rate processes, 1941.

J. Bartos and Z. Hlouskova, Study of conformational-segmental mobility in linear polyethylene and isotactic polypropylene by the spin probe method, Colloid & Polymer Science, vol.50, issue.7, p.624, 1988.
DOI : 10.1007/BF01411503

R. Boyd and S. Breitling, The Conformational Analysis of Crankshaft Motions in Polyethylene, Macromolecules, vol.7, issue.6, p.855, 1974.
DOI : 10.1021/ma60042a032

A. T. Hagler, P. Dauber, and S. Lifson, Consistent force field studies of intermolecular forces in hydrogen-bonded crystals. 3. The C:O.cntdot..cntdot..cntdot.H-O hydrogen bond and the analysis of the energetics and packing of carboxylic acids, Journal of the American Chemical Society, vol.101, issue.18, p.5131, 1979.
DOI : 10.1021/ja00512a003

R. L. Grimm, D. J. Tobias, and J. Hemminger, O Water Interaction with Textured Carboxylic Acid-Terminated Monolayer Surfaces Characterized by Temperature-Programmed Desorption and Molecular Dynamics, The Journal of Physical Chemistry C, vol.114, issue.3, p.1570, 2010.
DOI : 10.1021/jp9064642

R. Boyd, Molecular basis of transitions and relaxations (Midland Macromolecular Monographs, p.277, 1978.

A. Yelon, B. Movaghar, and R. Crandall, Multi-excitation entropy: its role in thermodynamics and kinetics, Reports on Progress in Physics, vol.69, issue.4, p.1145, 2006.
DOI : 10.1088/0034-4885/69/4/R04

C. S. Levin, B. G. Janesko, R. Bardhan, G. E. Scuseria, J. D. Hartgerink et al., Chain-Length-Dependent Vibrational Resonances in Alkanethiol Self-Assembled Monolayers Observed on Plasmonic Nanoparticle Substrates, Nano Letters, vol.6, issue.11, p.2617, 2006.
DOI : 10.1021/nl062283k