Synthesis, Chemistry, and Photochemistry of Methylcyanobutadiyne in the Context of Space Science

Abstract : An alternative preparation of methylcyanobutadiyne (MeC5N), a molecule present in the interstellar medium, was established in order to circumvent tedious steps from previous methods. The possibility of forming methylcyanoacetylene and MeC5N by gas-phase photolysis was evaluated from relevant acetylene derivatives in the context of space science. The reactivity of MeC5N toward simple nucleophiles was investigated. The exclusive formation of E adducts was observed, together with a solvent dependence for the regioselectivity of the addition
Document type :
Journal articles
Complete list of metadatas

https://hal-univ-rennes1.archives-ouvertes.fr/hal-01307764
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, April 26, 2016 - 5:17:50 PM
Last modification on : Saturday, December 22, 2018 - 7:32:10 PM

Identifiers

Citation

Nicolas Kerisit, Cédric Rouxel, Sophie Colombel-Rouen, Loic Toupet, Jean-Claude Guillemin, et al.. Synthesis, Chemistry, and Photochemistry of Methylcyanobutadiyne in the Context of Space Science. Journal of Organic Chemistry, American Chemical Society, 2016, ⟨10.1021/acs.joc.6b00205⟩. ⟨hal-01307764⟩

Share

Metrics

Record views

412