Synthesis, Chemistry, and Photochemistry of Methylcyanobutadiyne in the Context of Space Science

Abstract : An alternative preparation of methylcyanobutadiyne (MeC5N), a molecule present in the interstellar medium, was established in order to circumvent tedious steps from previous methods. The possibility of forming methylcyanoacetylene and MeC5N by gas-phase photolysis was evaluated from relevant acetylene derivatives in the context of space science. The reactivity of MeC5N toward simple nucleophiles was investigated. The exclusive formation of E adducts was observed, together with a solvent dependence for the regioselectivity of the addition
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Article dans une revue
Journal of Organic Chemistry, American Chemical Society, 2016, 〈10.1021/acs.joc.6b00205〉
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01307764
Contributeur : Laurent Jonchère <>
Soumis le : mardi 26 avril 2016 - 17:17:50
Dernière modification le : samedi 22 décembre 2018 - 19:32:10

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Nicolas Kerisit, Cédric Rouxel, Sophie Colombel-Rouen, Loic Toupet, Jean-Claude Guillemin, et al.. Synthesis, Chemistry, and Photochemistry of Methylcyanobutadiyne in the Context of Space Science. Journal of Organic Chemistry, American Chemical Society, 2016, 〈10.1021/acs.joc.6b00205〉. 〈hal-01307764〉

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