Synthesis, Chemistry, and Photochemistry of Methylcyanobutadiyne in the Context of Space Science

Nicolas Kerisit 1 Cédric Rouxel 1 Sophie Colombel-Rouen 1 Loic Toupet 2 Jean-Claude Guillemin 1 Yann Trolez 1
1 ISCR - Institut des Sciences Chimiques de Rennes
2 IPR - Institut de Physique de Rennes
Abstract : An alternative preparation of methylcyanobutadiyne (MeC5N), a molecule present in the interstellar medium, was established in order to circumvent tedious steps from previous methods. The possibility of forming methylcyanoacetylene and MeC5N by gas-phase photolysis was evaluated from relevant acetylene derivatives in the context of space science. The reactivity of MeC5N toward simple nucleophiles was investigated. The exclusive formation of E adducts was observed, together with a solvent dependence for the regioselectivity of the addition
Type de document :
Article dans une revue
Journal of Organic Chemistry, American Chemical Society, 2016, 〈10.1021/acs.joc.6b00205〉
Domaine :
Liste complète des métadonnées
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01307764
Contributeur : Laurent Jonchère <>
Soumis le : mardi 26 avril 2016 - 17:17:50
Dernière modification le : samedi 22 décembre 2018 - 19:32:10

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UNIV-RENNES1 | ISCR | IPR | UR1-UFR-SPM | ISCR-OMC | INC-CNRS | ISCR-CORINT | OSUR | UNIV-RENNES | INSA-RENNES

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Nicolas Kerisit, Cédric Rouxel, Sophie Colombel-Rouen, Loic Toupet, Jean-Claude Guillemin, et al.. Synthesis, Chemistry, and Photochemistry of Methylcyanobutadiyne in the Context of Space Science. Journal of Organic Chemistry, American Chemical Society, 2016, 〈10.1021/acs.joc.6b00205〉. 〈hal-01307764〉

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