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Design of ruthenium-alkynyl complexes as nonlinear optical chromophores

Abstract : This review paper focuses on the design and non linear optical properties of trans-Ru(dppe)2 (dppe = 1,2-bis(diphenylphosphino)ethane) alkynyl complexes and their derivatives. These systems constitute remarkable second and third-order non linear optical active chromophores. Furthermore, modifying the environment around the ruthenium affords the possibility of tuning their non linear optical performances and accessing facile non linear optical switching. The coverage is focused on quadratic (second-order) and cubic (third-order) non linear optical properties measured at molecular level from solution studies as well as on non linear optical properties of bulk materials
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01326293
Contributor : Laurent Jonchère <>
Submitted on : Friday, June 3, 2016 - 2:02:12 PM
Last modification on : Friday, July 10, 2020 - 4:21:44 PM

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  • HAL Id : hal-01326293, version 1

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Jean-Luc Fillaut. Design of ruthenium-alkynyl complexes as nonlinear optical chromophores. Display and Imaging, 2016, 2, pp.115--134. ⟨hal-01326293⟩

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