R. Plummer, P. Lorigan, N. Steven, L. Scott, M. R. Middleton et al., A phase II study of the potent PARP inhibitor, Rucaparib (PF-01367338, AG014699), with temozolomide in patients with metastatic melanoma demonstrating evidence of chemopotentiation, Cancer Chemotherapy and Pharmacology, vol.17, issue.5, pp.1191-1199, 2013.
DOI : 10.1007/s00280-013-2113-1

). S. Labadie and E. Teng, Indol-2-yltributylstannane: A Versatile Reagent for 2-Substituted Indoles, The Journal of Organic Chemistry, vol.59, issue.15, pp.4250-4254, 1994.
DOI : 10.1021/jo00094a042

J. L. Hudkins, F. D. Diebold, and . Marsh, Synthesis Of 2-Aryl- and 2-Vinyl-1H-indoles via Palladium-Catalyzed Cross-Coupling of Aryl and Vinyl Halides with 1-Carboxy-2-(tributylstannyl)indole, The Journal of Organic Chemistry, vol.60, issue.19, pp.6218-6220, 1995.
DOI : 10.1021/jo00124a048

G. A. Molander, B. Canturk, and L. E. Kennedy, Scope of the Suzuki???Miyaura Cross-Coupling Reactions of Potassium Heteroaryltrifluoroborates, The Journal of Organic Chemistry, vol.74, issue.3, pp.973-980, 2008.
DOI : 10.1021/jo802590b

M. S. Liu, H. Mudadu, R. Schmider, Y. Thummel, S. Tao et al., Tuning the Luminescence and Electroluminescence of Diphenylboron Complexes of 5-Substituted 2-(2???-Pyridyl)indoles, Organometallics, vol.21, issue.22, pp.4743-4749, 2002.
DOI : 10.1021/om020446j

F. Bellina, S. Cauteruccio, R. Rossi, F. Kakiuchi, and T. Kochi, Development and Application of Effective Protocols for the Synthesis of Arylheteroarenes and Biheteroaryls, Including Bioactive Derivatives, by Highly Regioselective Transition Metal-Catalyzed Direct Intermolecular Arylation Reactions of Five-Membered Heteroarenes with (Hetero)aryl Halides, Current Organic Chemistry, vol.12, issue.9, pp.774-790, 2008.
DOI : 10.2174/138527208784567205

R. Ackermann, A. R. Vicente, and . Kapdi, Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by C??????H Bond Cleavage, Angewandte Chemie International Edition, vol.44, issue.52, pp.9792-9826, 2009.
DOI : 10.1002/anie.200902996

T. W. Lyons and M. S. Sanford, Palladium-Catalyzed Ligand-Directed C???H Functionalization Reactions, Chemical Reviews, vol.110, issue.2, pp.1147-1169, 2010.
DOI : 10.1021/cr900184e

E. M. Beck and M. J. Gaunt, Pd-Catalyzed C???H Bond Functionalization on the Indole and Pyrrole Nucleus, Top. Curr. Chem, vol.292, pp.85-121, 2010.
DOI : 10.1007/128_2009_15

J. Yuan, H. Soulé, and . Doucet, Functionalization of C???H Bonds via Metal-Catalyzed Desulfitative Coupling: An Alternative Tool for Access to Aryl- or Alkyl-Substituted (Hetero)arenes, ACS Catalysis, vol.5, issue.2, pp.978-991, 2015.
DOI : 10.1021/cs501686d
URL : https://hal.archives-ouvertes.fr/hal-01114983

L. Bheeter, J. Chen, H. Soulé, and . Doucet, Regioselectivity in palladium-catalysed direct arylation of 5-membered ring heteroaromatics, Catal. Sci. Technol., vol.48, issue.7, pp.2005-2049, 2016.
DOI : 10.1039/C5CY02095F
URL : https://hal.archives-ouvertes.fr/hal-01274107

). B. Touré, B. S. Lane, and D. Sames, Catalytic C???H Arylation of SEM-Protected Azoles with Palladium Complexes of NHCs and Phosphines, Organic Letters, vol.8, issue.10, pp.1979-1982, 2006.
DOI : 10.1021/ol053021c

). F. Bellina, C. Calandri, S. Cauteruccio, R. Rossid-)-l, L. Joucla et al., Boorman and I. Larrosa, Progress in Heterocyclic Chemistry, Tetrahedron Lebrasseur and I. Larrosa, J. Am. Chem. Soc. Adv. Synth. Catal. Adv. Synth. Catal. Chem. Commun. Chem. Eur. J, vol.63, issue.19, pp.2926-2927, 1970.

). G. Molander and N. Ellis, Organotrifluoroborates:?? Protected Boronic Acids That Expand the Versatility of the Suzuki Coupling Reaction, Accounts of Chemical Research, vol.40, issue.4, pp.275-286, 2007.
DOI : 10.1021/ar050199q

D. Yang, C. L. Sun, Z. Fang, B. J. Li, Y. Z. Li et al., Palladium-Catalyzed Direct Arylation of (Hetero)Arenes with Aryl Boronic Acids, Angewandte Chemie, vol.19, issue.8, pp.1495-1498, 2008.
DOI : 10.1002/ange.200704619

N. R. Deprez, D. Kalyani, A. Krause, M. S. Sanford, and J. Am, Room Temperature Palladium-Catalyzed 2-Arylation of Indoles, Journal of the American Chemical Society, vol.128, issue.15, pp.4972-4973, 2006.
DOI : 10.1021/ja060809x

Z. Liang, B. Yao, and Y. Zhang, -Catalyzed Regioselective Arylation of Indoles with Arylsiloxane in Acidic Medium, Organic Letters, vol.12, issue.14, pp.3185-3187, 2010.
DOI : 10.1021/ol101147b
URL : https://hal.archives-ouvertes.fr/hal-00109057

M. Miyasaka, A. Fukushima, T. Satoh, K. Hirano, and M. Miura, Fluorescent Diarylindoles by Palladium-Catalyzed Direct and Decarboxylative Arylations of Carboxyindoles, Chemistry - A European Journal, vol.47, issue.15, pp.3674-3677, 2009.
DOI : 10.1002/chem.200900098

M. Wu, J. Luo, F. Xiao, S. Zhang, G. J. Deng et al., Palladium-Catalyzed Direct and Site-Selective Desulfitative Arylation of Indoles with Sodium Sulfinates, Advanced Synthesis & Catalysis, vol.140, issue.2-3, pp.335-340, 2012.
DOI : 10.1002/adsc.201100603

T. Miao, P. Li, G. W. Wang, and L. Wang, Microwave-Accelerated Pd-Catalyzed Desulfitative Direct C2-Arylation of Free (NH)-Indoles with Arylsulfinic Acids, Chemistry - An Asian Journal, vol.52, issue.12, pp.3185-3190, 2013.
DOI : 10.1002/asia.201300913

D. R. Stuart, E. Villemure, K. Fagnou, J. S. Potavathri, K. C. Pereira et al., Elements of Regiocontrol in Palladium-Catalyzed Oxidative Arene Cross-Coupling, Journal of the American Chemical Society, vol.129, issue.40, pp.12072-12073, 2007.
DOI : 10.1021/ja0745862

C. Wong and S. C. Zimmerman, Orthogonality in organic, polymer, and supramolecular chemistry: from Merrifield to click chemistry, Chemical Communications, vol.8, issue.17, pp.1679-1695, 2013.
DOI : 10.1039/c2cc37316e

X. Zhao, E. Dimitrijevi?, and V. M. Dong, Palladium-Catalyzed C???H Bond Functionalization with Arylsulfonyl Chlorides, Journal of the American Chemical Society, vol.131, issue.10, pp.3466-3467, 2009.
DOI : 10.1021/ja900200g

M. Zhang, S. Zhang, M. Liu, and J. Cheng, Palladium-catalyzed desulfitative C-arylation of a benzo[d]oxazole C???H bond with arene sulfonyl chlorides, Chemical Communications, vol.132, issue.41, pp.11522-11524, 2011.
DOI : 10.1039/c1cc14718h

W. Hagui, K. Yuan, N. Besbes, E. Srasra, J. Soulé et al., Palladium-Catalyzed Iterative C???H Bond Arylations: Synthesis of Medium-Size Heterocycles with a Bridgehead Nitrogen Atom, ChemCatChem, vol.11, issue.21, pp.3544-3554, 2015.
DOI : 10.1002/cctc.201500652
URL : https://hal.archives-ouvertes.fr/hal-01216288

A. Hfaiedh, K. Yuan, H. Ben-ammar, B. Ben-hassine, J. Soulé et al., Eco-Friendly Solvents for Palladium-Catalyzed Desulfitative C???H Bond Arylation of Heteroarenes, ChemSusChem, vol.120, issue.10, pp.1794-1804, 2015.
DOI : 10.1002/cssc.201403429
URL : https://hal.archives-ouvertes.fr/hal-01146125

B. Liégault, I. Petrov, S. I. Gorelsky, and K. Fagnou, Modulating Reactivity and Diverting Selectivity in Palladium-Catalyzed Heteroaromatic Direct Arylation Through the Use of a Chloride Activating/Blocking Group, The Journal of Organic Chemistry, vol.75, issue.4, pp.1047-1060, 2010.
DOI : 10.1021/jo902515z

K. Müller, C. Faeh, and F. Diederich, Fluorine in Pharmaceuticals: Looking Beyond Intuition, Science, vol.317, issue.5846, pp.1881-1886, 2007.
DOI : 10.1126/science.1131943

A. A. Haddach, A. Kelleman, and M. V. Deaton-rewolinski, An efficient method for the N-debenzylation of aromatic heterocycles, Tetrahedron Letters, vol.43, issue.3, pp.399-402, 2002.
DOI : 10.1016/S0040-4039(01)02192-X

T. Cantat, E. Génin, C. Giroud, G. Meyer, and A. Jutand, Structural and kinetic effects of chloride ions in the palladium-catalyzed allylic substitutions, Journal of Organometallic Chemistry, vol.687, issue.2, pp.365-376, 2003.
DOI : 10.1016/S0022-328X(03)00791-5

D. Nandi, Y. Jhou, J. Lee, B. Kuo, C. Liu et al., Pd(0)-Catalyzed Decarboxylative Coupling and Tandem C???H Arylation/Decarboxylation for the Synthesis of Heteroaromatic Biaryls, The Journal of Organic Chemistry, vol.77, issue.20, pp.9384-9390, 2012.
DOI : 10.1021/jo3015837

L. Ackermann, S. Barfüßer, and H. K. Potukuchi, -Arylation/Hydroamin(d)ation Domino Synthesis of Indoles and its Application to the Preparation of a Chek1/KDR Kinase Inhibitor Pharmacophore, Advanced Synthesis & Catalysis, vol.68, issue.7-8, pp.1064-1072, 2009.
DOI : 10.1002/adsc.200900004
URL : https://hal.archives-ouvertes.fr/in2p3-00459366