Direct synthesis of dicarbonyl PCP-iron hydride complexes and catalytic dehydrogenative borylation of styrene - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2016

Direct synthesis of dicarbonyl PCP-iron hydride complexes and catalytic dehydrogenative borylation of styrene

Résumé

A new and efficient method based on the simple metalating reagent Fe(CO)(5) has been developed for the straightforward synthesis of well defined cyclometalled PCP iron carbonyl pincer complexes. The reaction proceeds cleanly under mild conditions at 30 degrees C and UV irradiation. Four hydride pincer complexes are synthesized and fully characterized as well as an intermediate dinuclear species. The new iron complexes are active and selective catalytic precursors for the dehydrogenative borylation of styrene with HBpin.
Fichier non déposé

Dates et versions

hal-01357395 , version 1 (29-08-2016)

Identifiants

Citer

Shi Jiang, Samuel Quintero-Duque, Thierry Roisnel, Vincent Dorcet, Mary Grellier, et al.. Direct synthesis of dicarbonyl PCP-iron hydride complexes and catalytic dehydrogenative borylation of styrene. Dalton Transactions, 2016, 45 (27), pp.11101--11108. ⟨10.1039/c6dt01149g⟩. ⟨hal-01357395⟩
42 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More