The millimeter wave spectrum of methyl cyanate: a laboratory study and astronomical search in space

L. Kolesnikova , J. L. Alonso , C. Bermudez , E. R. Alonso , B. Tercero (1) , J. Cernicharo (1) , J. -C. Guillemin (2)

1 ICMM - Instituto de Ciencia de Materiales de Madrid
2 ISCR - Institut des Sciences Chimiques de Rennes

Aims. The recent discovery of methyl isocyanate (CH3NCO) in Sgr B-2(N) and Orion KL makes methyl cyanate (CH3OCN) a potential molecule in the interstellar medium. The aim of this work is to fulfill the first requirement for its unequivocal identification in space, i.e. the availability of transition frequencies with high accuracy. Methods. The room-temperature rotational spectrum of methyl cyanate was recorded in the millimeter wave domain from 130 to 350 GHz. All rotational transitions revealed A-E splitting owing to methyl internal rotation and were globally analyzed using the ERHAM program. Results. The data set for the ground torsional state of methyl cyanate exceeds 700 transitions within J '' = 10-35 and K ''(a) = 0-13 and newly derived spectroscopic constants reproduce the spectrum close to the experimental uncertainty. Spectral features of methyl cyanate were then searched for in Orion KL, Sgr B2(N), B1-b, and TMC-1 molecular clouds. Upper limits to the column density of methyl cyanate are provided.

Mots clés: orion-kl; microwave-spectrum; interstellar detection; molecular-structure; fulminic acid; dark clouds; ether; hocn; spectroscopy; discovery

Domaines: Chimie

L. Kolesnikova, J. L. Alonso, C. Bermudez, E. R. Alonso, B. Tercero, et al.. The millimeter wave spectrum of methyl cyanate: a laboratory study and astronomical search in space. Astronomy and Astrophysics - A&A, 2016, 591, pp.A75. ⟨10.1051/0004-6361/201628140⟩. ⟨hal-01357413⟩