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Contrasted photochromic and luminescent properties in dinuclear Pt(II) complexes linked through a central dithienylethene unit

J. Boixel 1 Y. Zhu H. Le Bozec 1 M.A. Benmensour 1 A. Boucekkine 1 K.M.-C. Wong A. Colombo D. Roberto V. Guerchais 1 D. Jacquemin 2
1 ISCR - Institut des Sciences Chimiques de Rennes
2 CEISAM - Chimie Et Interdisciplinarité : Synthèse, Analyse, Modélisation
Abstract : We disclose two unprecedented complexes built with a central dithienylethene photochrome connecting two cyclometalated Pt(ii) moieties either on the reactive carbon atoms or on the lateral non-reactive carbon atoms of the photochrome. The two systems show vastly different properties that are rationalised thanks to quantum-chemical calculations. © The 2016 The Royal Society of Chemistry.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01367210
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Submitted on : Thursday, September 15, 2016 - 5:16:58 PM
Last modification on : Thursday, March 5, 2020 - 2:05:52 PM

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UNIV-RENNES1 | ISCR | CNRS | UNIV-NANTES | ISCR-CTI | UR1-UFR-SPM | ISCR-OMC | INC-CNRS | UNIV-RENNES | INSA-GROUPE

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J. Boixel, Y. Zhu, H. Le Bozec, M.A. Benmensour, A. Boucekkine, et al.. Contrasted photochromic and luminescent properties in dinuclear Pt(II) complexes linked through a central dithienylethene unit. Chemical Communications, Royal Society of Chemistry, 2016, 52 (63), pp.9833--9836. ⟨10.1039/c6cc03431d⟩. ⟨hal-01367210⟩

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