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Modular Synthesis of Arylacetic Acid Esters, Thioesters, and Amides from Aryl Ethers via Rh(II)-Catalyzed Diazo Arylation

Abstract : One-pot formation of arylacetic acid esters, thioesters, and amides via Rh(II)-catalyzed arylation of a Meldrum's acid-derived diazo reagent with electron-rich arenes is described. The methodology was used to efficiently synthesize an anticancer compound. © 2016 American Chemical Society.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01367227
Contributor : Laurent Jonchère <>
Submitted on : Thursday, September 15, 2016 - 5:17:32 PM
Last modification on : Thursday, March 5, 2020 - 3:14:53 PM

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D. Best, M. Jean, P. van de Weghe. Modular Synthesis of Arylacetic Acid Esters, Thioesters, and Amides from Aryl Ethers via Rh(II)-Catalyzed Diazo Arylation. Journal of Organic Chemistry, American Chemical Society, 2016, 81 (17), pp.7760--7770. ⟨10.1021/acs.joc.6b01426⟩. ⟨hal-01367227⟩

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