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Anisyl-, aminophenyl-, and naphthylmethylsilatranes revisited

Abstract : Three Si-substituted silatranes were synthesized in order to rectify their structure with particular attention to the length of the N-Si intramolecular dative bond. DFT calculations of potential energy profile as a function of the N-Si distance and the structure of HOMO were considered. The latter was found to vary its localization depending on the electron-donating properties of the substituent and the N-Si distance.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01395465
Contributor : Laurent Jonchère <>
Submitted on : Thursday, November 10, 2016 - 5:09:56 PM
Last modification on : Thursday, March 5, 2020 - 2:06:34 PM

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Yu Wang, Vitalijs Romanovs, Jana Spura, Lubova Ignatovica, Thierry Roisnel, et al.. Anisyl-, aminophenyl-, and naphthylmethylsilatranes revisited. Chemistry of Heterocyclic Compounds, Springer Verlag, 2016, 52 (8), pp.546--550. ⟨10.1007/s10593-016-1928-1⟩. ⟨hal-01395465⟩

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