Immobilization of Monolayers Incorporating Cu Funnel Complexes onto Gold Electrodes. Application to the Selective Electrochemical Recognition of Primary Alkylamines in Water

Gael de Leener (1, 2) , Ferdinand Evoung-Evoung (3) , Angelique Lascaux (1) , Jérémy Mertens (4) , Ana Gabriela Porras-Gutierrez (3) , Nicolas Le Poul (3) , Corinne Lagrost (5) , Diana Over (2) , Yann Leroux (5) , François Reniers (4) , Philippe Hapiot (5) , Yves Le Mest (3) , Ivan Jabin (1) , Olivia Reinaud (2)

1 Laboratoire de Chimie Organique
2 LCBPT - UMR 8601 - Laboratoire de Chimie et de Biochimie Pharmacologiques et Toxicologiques
3 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique
4 CHANI - Service de chimie analytique et chimie des interfaces
5 ISCR - Institut des Sciences Chimiques de Rennes

Keywords: self-assembled monolayers; aliphatic-amines; induced electroclick; beta-cyclodextrin; neutral molecules; aqueous-solution; metal-surfaces; copper complex; alkyl amines; active-sites

Domains: Chemical Sciences

Gael de Leener, Ferdinand Evoung-Evoung, Angelique Lascaux, Jérémy Mertens, Ana Gabriela Porras-Gutierrez, et al.. Immobilization of Monolayers Incorporating Cu Funnel Complexes onto Gold Electrodes. Application to the Selective Electrochemical Recognition of Primary Alkylamines in Water. Journal of the American Chemical Society, 2016, 138 (39), pp.12841--12853. ⟨10.1021/jacs.6b05317⟩. ⟨hal-01395479⟩