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Article Dans Une Revue Physical Chemistry Chemical Physics Année : 2016

Metallic cyanoacetylides of copper, silver and gold: Generation and structural characterization

C. Cabezas
C. Barrientos
  • Fonction : Auteur
A. Largo
  • Fonction : Auteur
J.L. Alonso
  • Fonction : Auteur

Résumé

The metallic cyanoacetylides CuCCCN, AgCCCN, and AuCCCN have been synthesized in the throat of a pulsed supersonic expansion by reaction of metal vapors, produced by laser ablation, and BrCCCN. Their pure rotational spectra in the (X1Σ+) electronic ground state were observed by Fourier transform microwave spectroscopy in the 2-10 GHz frequency region. Importantly, the rotational spectroscopy constants determined from the analysis of the rotational spectra clearly established the existence of metal-CCCN arrangements for all the mentioned cyanoacetylides. A study of the chemical bonding by means of a topological analysis of the electron density helps to understand the preference for metal-C bonding over metal-N bonding. © the Owner Societies 2016.

Domaines

Chimie

Dates et versions

hal-01398034 , version 1 (16-11-2016)

Identifiants

Citer

C. Cabezas, C. Barrientos, A. Largo, J.-C. Guillemin, J.L. Alonso. Metallic cyanoacetylides of copper, silver and gold: Generation and structural characterization. Physical Chemistry Chemical Physics, 2016, 18 (41), pp.28538--28547. ⟨10.1039/c6cp04474c⟩. ⟨hal-01398034⟩
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