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Conference papers
Low energy phonon spectroscopy and translation-rotation coupling in hybrid perovskites crystals
Antoine Létoublon
1
Serge Paofai
2
Philippe Bourges
3
Stéphane Cordier
2
Olivier Durand
1
Benoit Rufflé
4
Claude Ecolivet
5
Marcelo Carignano
6
Claudine Katan
2
Jacky Even
1
Antoine Létoublon 1
Author IdHAL : antoine-letoublon
Serge Paofai 2
Author IdHAL : serge-paofai ORCID : https://orcid.org/0000-0001-9966-156X
Philippe Bourges 3
Author
Stéphane Cordier 2
Author IdHAL : cordier-stephane ORCID : https://orcid.org/0000-0003-0707-3774
Olivier Durand 1
Author IdHAL : olivier-durand
Benoit Rufflé 4
Author
Claude Ecolivet 5
Author IdHAL : claude-ecolivet ResearcherId : http://www.researcherid.com/rid/N-8640-2014 ORCID : https://orcid.org/0000-0002-1929-7655
Marcelo Carignano 6
Author
Claudine Katan 2
Author IdHAL : katan ResearcherId : http://www.researcherid.com/rid/I-9446-2012 ORCID : https://orcid.org/0000-0002-2017-5823
Jacky Even 1
Author IdHAL : jacky-even ResearcherId : http://www.researcherid.com/rid/ C-6212-2008 ORCID : https://orcid.org/0000-0002-4607-3390
1
FOTON - Fonctions Optiques pour les Technologies de l'informatiON (ENSSAT 6, rue de Kerampont CS 80518 22305 LANNION Cedex - France)
- UR1 - Université de Rennes 1 (2 rue du Thabor - CS 46510 - 35065 Rennes cedex - France)
- UNIV-RENNES - Université de Rennes (France)
- UEB - Université européenne de Bretagne - European University of Brittany (5 boulevard Laënnec - 35000 Rennes - France)
- INSA Rennes - Institut National des Sciences Appliquées - Rennes (20, avenue des Buttes de Coësmes - CS 70839 - 35708 Rennes cedex 7 - France)
- ENSSAT - École Nationale Supérieure des Sciences Appliquées et de Technologie (6 rue de Kerampont - BP 80518 - 22305 Lannion Cedex - France)
- Télécom Bretagne (Technopôle Brest-Iroise CS 83818 29238 BREST Cedex 3 - France)
- CNRS - Centre National de la Recherche Scientifique : UMR6082 (France)
2
ISCR - Institut des Sciences Chimiques de Rennes (Campus de Beaulieu - Bât. 10 Avenue du Général Leclerc 35042 Rennes Cedex - France)
- UR1 - Université de Rennes 1 (2 rue du Thabor - CS 46510 - 35065 Rennes cedex - France)
- UNIV-RENNES - Université de Rennes (France)
- INSA Rennes - Institut National des Sciences Appliquées - Rennes (20, avenue des Buttes de Coësmes - CS 70839 - 35708 Rennes cedex 7 - France)
- Ecole Nationale Supérieure de Chimie de Rennes (France)
- CNRS - Centre National de la Recherche Scientifique : UMR6226 (France)
3
LLB - UMR 12 - Laboratoire Léon Brillouin (LLB - UMR 12, CEA Saclay 91191 GIF SUR YVETTE CEDEX - France)
- CEA - Commissariat à l'énergie atomique et aux énergies alternatives : DRF/IRAMIS (Centre de Saclay Centre de Grenoble Centre de Cadarache etc - France)
- Université Paris-Saclay (Espace Technologique, Bat. Discovery - RD 128 - 2e ét., 91190 Saint-Aubin - France)
- CNRS - Centre National de la Recherche Scientifique : UMR12 (France)
4
L2C - Laboratoire Charles Coulomb (1 place Eugène Bataillon Université Montpellier 34095 Montpellier Cedex 5 - France)
- UM - Université de Montpellier : HR10M00506 (163 rue Auguste Broussonnet - 34090 Montpellier - France)
- CNRS - Centre National de la Recherche Scientifique : UMR5221 (France)
5
IPR - Institut de Physique de Rennes (Bâtiment 11A , B, C, E – 10B
263 av. Général Leclerc
35042 Rennes cedex FRANCE - France)
- UR1 - Université de Rennes 1 (2 rue du Thabor - CS 46510 - 35065 Rennes cedex - France)
- UNIV-RENNES - Université de Rennes (France)
- CNRS - Centre National de la Recherche Scientifique : UMR6251 (France)
6
QEERI - Qatar Environment and Energy Research Institute (Hamad Bin Khalifa University,
Doha - Qatar)
Abstract : Despite the wealth of research conducted the last three years on hybrid organic perovskites (HOP), several questions remain open including: to what extend the organic moiety changes the properties of the material as compared to all-inorganic (AIP) related perovskite structures. To ultimately reach an answer to this question, we have recently introduced two approaches that were designed to take the stochastic molecular degrees of freedom into account, and suggested that the high temperature cubic phase of HOP and AIP is an appropriate reference phase to rationalize HOP's properties. In this paper, we recall the main concepts and show recent molecular dynamic results (figure 1) to discuss more specifically the various possible couplings between charge carriers and low energy excitations such as acoustic and optical phonons. As available experimental or simulated data on low energy excitations are limited, we also present preliminary neutron and Brillouin scattering, as well as ultrasonic measurements obtained on freshly prepared single crystals of CH 3 NH 3 PbBr 3.
Document type :
Conference papers
Domain :
Complete list of metadatas
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01416169
Contributor : Claudine Katan <>
Submitted on : Thursday, January 26, 2017 - 5:40:18 PM
Last modification on : Thursday, January 14, 2021 - 3:33:34 AM
Contributor : Claudine Katan <>
Submitted on : Thursday, January 26, 2017 - 5:40:18 PM
Last modification on : Thursday, January 14, 2021 - 3:33:34 AM
Identifiers
- HAL Id : hal-01416169, version 1
Collections
CNRS | INSTITUT-TELECOM | DSM-IRAMIS | L2C | IPR | ISCR | UNIV-RENNES1 | ISCR-CTI | CEA | IRAMIS-LLB | INC-CNRS | ISCR-CSM | UR1-UFR-SPM | FOTON | FOTON_OHM | IPR-ML | OSUR | MIPS | UNIV-MONTPELLIER | CEA-DRF | CEA-UPSAY | UNIV-RENNES | FOTON-INSA | INSA-RENNES | INSA-GROUPE
Citation
Antoine Létoublon, Serge Paofai, Philippe Bourges, Stéphane Cordier, Olivier Durand, et al.. Low energy phonon spectroscopy and translation-rotation coupling in hybrid perovskites crystals. 2è Journées Pérovskites Hybrides (JPH 2016), May 2016, Rennes, France. ⟨hal-01416169⟩
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