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Hydrogenation of Carbonyl Derivatives with a Well-Defined Rhenium Precatalyst

Abstract : The first efficient and general rhenium-catalyzed hydrogenation of carbonyl derivatives was developed. The key to the success of the reaction was the use of a well-defined rhenium complex bearing a tridentate diphosphinoamino ligand as the catalyst (0.5 mol %) at 70 °C in the presence of H2 (30 bar). The mechanism of the reaction was investigated by DFT(PBE0-D3) calculations.
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Duo Wei, Thierry Roisnel, Christophe Darcel, Eric Clot, Jean-Baptiste Sortais. Hydrogenation of Carbonyl Derivatives with a Well-Defined Rhenium Precatalyst. ChemCatChem, Wiley, 2017, 9 (1), pp.80-83. ⟨10.1002/cctc.201601141⟩. ⟨hal-01435008⟩

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